Smart 1000 ccd area diffractometer

Starting materials, reagents and solvents with AR grade were purchased from commercial suppliers and used without further purification. Elemental analyses were performed on a Perkin-Elmer 240C elemental analyzer. IR spectra were recorded on a Jasco FT/IR-4000 spectrometer as KBr pellets in the 4000-400 cm -1 region. 1 (link) H NMR data were recorded on a Bruker 300 MHz instrument. X-ray diffraction was carried out on a Bruker SMART 1000 CCD area diffractometer.

All solvents used were of AR grade and used as received. 4-Bromosalicyaldehyde, 2-(2-aminoethylamino) ethanol, copper acetate monohydrate, copper chloride dihydrate and sodium azide were purchased from Aladin Chemical Co. Ltd. and were used as received. Styrene, cyclooctene, cyclohexene and TBHP were purchased from Aldrich and were used as received. Infrared spectra (4000-400 cm -1 ) were recorded as KBr discs with a FTS-40 Bio-Rad FT-IR spectrophotometer. The electronic spectra were recorded on a Lambdar 35 spectrometer. Microanalyses (C, H, N) of the complex were carried out on a Carlo-Erba 1106 elemental analyzer. Solution electrical conductivity was measured at 298K using a DDS-11 conductivity meter. GC analyses were performed on a Shimadzu GC-2010 gas chromatograph. Crystallographic data of the complexes were collected on a Bruker SMART 1000 CCD area diffractometer with graphite monochromated Mo-Kα radiation (λ = 0.71073 Å) at 298(2) K.
Caution! Transition metal azido complexes are potentially explosive especially in the presence of organic ligands. Although we have not encountered any problem during our study, yet a small quantity of materials should be prepared and it should be handled with care.

Starting materials, reagents, and solvents of AR grade were purchased from commercial suppliers and used without further purification. Elemental analyzes were performed using a Perkin-Elmer 240C elemental analyzer. IR spectra were recorded as KBr pellets in the 4000-400 cm -1 range using a Jasco FT/IR-4000 spectrometer. 1 (link) H NMR data were recorded using a Bruker 300 MHz instrument and X-ray diffraction was performed with a Bruker SMART 1000 CCD area diffractometer.