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4 protocols using bis trimethylsilyl sulfide tms 2s

1

Synthesis of Cadmium Sulfide Nanoparticles

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All chemicals are commercially available and used as received without purification (except stated otherwise). Cadmium oxide (CdO, 99.99%), oleic acid (OA, 90%), ODE (90%), and bis(trimethylsilyl)sulfide ((TMS)2S) were purchased from Sigma-Aldrich. Cadmium acetate dihydride (Cd(OAc)2·2H2O, 99.999%) and the bulk cadmium sulfide (CdS, 98%) were from Alfa Aesar. Powder sulfur (S, 99.5%) and isopropanol (i-PrOH, 99.7%) were received from Chengdu Ke Long Chemical. Phenylacetic acid (PhCH2COOH, 98%) was from Sinopharm Chemical Reagent. DCTB (98.0%) and CHCA were obtained from Tokyo Chemical Industry. Toluene (99.5%) and cyclohexane (CH, 99.5%) were from Chengdu Ke Long Chemical; dried solvents were used for the kinetic study (with ~20 g of Na2SO4 for 1000 mL of solvents).
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2

Fabrication of Perovskite Solar Cells

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Lead(II) acetate trihydrate
(Pb(CH3COO)2·3H2O, 99.99%, Sigma-Aldrich),
bis(trimethylsilyl)sulfide
(TMS2S, Sigma-Aldrich), lead(II) iodide (PbI2, 99%, Sigma-Aldrich), formamidinium iodide (FAI, 99%, Sigma-Aldrich),
1-octadecene (ODE, 90%, Sigma-Aldrich), oleic acid (OA, 90%, Sigma-Aldrich), N-methylformamide (NMF, HCONHCH3, 99%, Sigma-Aldrich),
ethanol (Fluka), hexane (95%, Sigma-Aldrich), acetone (99.5%, Sigma-Aldrich),
titanium(IV) isopropoxide (TTIP, 97%, Sigma-Aldrich), hydrochloric
acid (HCL, Sigma-Aldrich), and methylammonium iodide (MAI, 98%, Sigma-Aldrich)
were used without further purification. Si/SiO2/graphene
substrates (Graphenea, Spain) were utilized for device fabrication.
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3

Synthesis of Semiconductor Nanocrystals

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All the following chemicals were used as received: cadmium oxide (CdO, 99.99%, Aldrich), lead (II) oxide (PbO, 99.999%, Alfa Aesar), selenium shot (Se, 99.999%, Alfa Aesar), bis(trimethylsilyl)sulfide ((TMS)2S, synthesis grade, Aldrich), oleic acid (OA, technical grade and 99% from Aldrich and Alfa Aesar, respectively), tetrachloroethylene (TCE, 99%, Aldrich), and 1-octadecene (ODE, technical grade, Aldrich).
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4

Colloidal Nanoparticle Synthesis

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Bismuth neodecanote, oleic acid (90 %), cadmium oxide (99.99 %), bis(trimethylsilyl) sulfide ((TMS)2S), hexadecylamine (90 %), tri-n-octylphosphine oxide (90 %), and trioctylphosphine (97 %) were purchased from Aldrich. Oleyl amine (90 %) was purchased from Aladdin. Thioacetamide and selenium powder were purchased from Sinopharm. 1,2-Dipalmitoyl-sn-glycero-3-phosphoethanol-amine-N-[methoxy(polyethylene glycol)-2000] (PEG-DSPE, 99 %) was purchased from Avanti. All chemicals were used as received, unless otherwise stated.
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