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2 protocols using 1 2 dichlorobenzene

1

Synthesis and Characterization of Functionalized Silica Particles

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Propylparaben, chlorobenzene, 1,2,4-trichlorobenzene, ethylbenzene, n-propylbenzene, n-butylbenzene, 3-aminopropyltriethoxysilane (APTES), phenol, 2,4-dimethylphenol, 2,4-dichlorophenol and glutaraldehyde solution (25%, V/V in water) were obtained from Aladdin Reagent Factory (Shanghai, China). Methylbenzene, 1,2-dichlorobenzene, sodium hydroxide (NaOH), thiourea, 1,4-dioxane, hydrochloric acid (HCl), sodium phosphate dibasic dodecahydrate (Na2HPO4·12H2O), and acetic acid (CH3COOH) were purchased from Sinopharm Group Chemical Reagent Co., Ltd. (Shanghai, China). Methylparaben and TAPB were obtained from Bidepharm (Shanghai, China). Ethylparaben, ibuprofen, and BPTA were purchased from Mackin (Shanghai, China). Flurbiprofen was purchased from HEOWNS (Tianjin, China). Diclofenac sodium was obtained from TCI (Shanghai, China). Phosphoric acid (H3PO4) was purchased from RHAWN (Shanghai, China). Acetonitrile and methanol were obtained from Tedia (Cincinnati, Ohio, USA). Fused silica capillaries (50 μm i.d. and 365 μm o.d.) were purchased from Ruifeng Chromatographic Devices (Yongnian, Hebei, China).
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2

Synthesis of Tris(4-Bromophenyl)Triazine

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2,4,6-Tris(4-bromophenyl)-1,3,5-triazine, n-BuLi, hydroxylamine hydrochloride (NH2OH·HCl), DBU, and triethylamine were purchased from Saan Chemical Technology (Shanghai) Co., Ltd. Benzaldehyde and 1,3,5-tris(bromomethyl)benzene were purchased from Jilin Chinese Academy of Sciences-Yanshen Technology Co., Ltd. Mesitylene, 1,4-dioxane, acetone, chloroform (CHCl3), tetrahydrofuran (THF), N,N-dimethylformamide, sodium bicarbonate, sodium cyanide, n-hexane, n-BuOH, NaOH, EtONa, Cs2CO3, piperidine, pyridine, 1,2-dichlorobenzene, and MgSO4 were purchased from Sinopharm Chemical Reagent Co., Ltd. Ultrapure water was prepared from the Millipore system (18.25 MΩ-cm). All the purchased reagents were of analytical grade and used without further purification.
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