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3 protocols using iron chloride hexahydrate

1

Bamboo-Based Functional Materials Synthesis

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The bamboo powder was ground from waste moso bamboo. Zinc acetate dihydrate (98%, C4H6O4Zn·2H2O), 2-methylimidazole (≥99.5%), iron chloride hexahydrate (99%, FeCl3·6H2O), iron chloride tetrahydrate (98%, FeCl2·4H2O), tetracycline (TC, 96% in purity) and choline chloride (C4H14ClNO, 98%) were purchased from Shanghai Macklin Biochemical Co., Ltd. (Shanghai, China). Oxalic acid dihydrate, sodium hydroxide (NaOH), and methanol were provided by Kelong Chemical Reagent Co., Ltd. (Chengdu, China). All the chemicals were used directly without further purification. Congo red (CR) was obtained from Sinopharm Chemical Regent Co., Ltd. (Shanghai, China).
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2

Synthesis of Metal-Organic Compounds

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Iron chloride hexahydrate (FeCl3·6H2O), manganese chloride hexahydrate (MnCl3·6H2O), cobalt nitrate hexahydrate (Co(NO3)2·6H2O), 2-methylimidazole (2-MIM), and tetracycline hydrochloride (TCH) were purchased from Macklin, China. Peroxymonosulfate (PMS) was obtained from Aladdin, China, and methanol (MeOH) was purchased from Shanghai Sinopharm Chemical Reagent Co., Ltd. All the reagents were used without further purification.
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3

Synthesis of Transition Metal Complexes

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2-Methylimidazole (AR, ≥98%), Sodium diethyldithiocarbamate (AR, ≥98%), Cobalt nitrate hexahydrate (Co(NO3)2·6H2O, AR, ≥99.7%), Copper nitrate trihydrate (Cu(NO3)2·3H2O, AR, ≥99.7%), Sodium 3-diethyldithiocarbamate trihydrate (DDTC), Iron chloride hexahydrate (FeCl3·6H2O, 99%), sulfate heptahydrate (FeSO4·7H2O, ≥98.0%), ammonia solution (AR, 25.0%–28.0%) were obtained from Shanghai Macklin Biochemical Co., Ltd. Absolute methanol (AR, ≥99.5%), Absolute ethanol (AR, ≥99.5%) were purchased from Tianjin Zhiyuan Chemical Reagent Co., Ltd.
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