γ cyclodextrin γ cd

γ-cyclodextrin (γ-CD) and methyl β-cyclodextrin (M-β-CD) were purchased from Sigma Aldrich (St. Louis, MI, USA). Apiol, dillapiol, allyltetramethoxybenzene and myristicin were isolated from plant extracts as described earlier [77 (link)]. Heparin (MM 50–80 kDa), organic solvents, salts and acids were from Reakhim (Moscow, Russia).
The synthesis of triphenylphosphine derivatives of allylbenzenes was performed as described earlier in the work [46 (link)].

α-cyclodextrin (α-CD) (≥98%, Sigma-Aldrich), β-cyclodextrin (β-CD) (≥97%, Sigma-Aldrich), γ-cyclodextrin (γ-CD) (≥98%, Sigma-Aldrich), 4-sulfocalix[4]arene sodium salt (SC[4]A) (≥98%, Tokyo Chemical Industry Ltd), ethylenediamine (EDA) (ReagentPlus, ≥99%, Sigma-Aldrich), 1,1′-carbonyldiimidazole (CDI) (≥97%, Sigma-Aldrich), TPC (≥98%, Sigma-Aldrich) and TMC (≥98%, Sigma-Aldrich) were used as received without further purification. Pure chlorophyll a and cannabidiol (CBD) solution (10 mg ml⁻¹ in ethanol) were purchased from Sigma-Aldrich. (+)-Limonene (>99%) was purchased from Tokyo Chemical Industry Ltd. Single crystal silicon wafers (phosphorous doped, (100) polished) from Si-Mat Germany were used as a substrate to deposit the free-standing nanofilms for AFM measurement. PLATYPUS silicon wafers with 100-nm-thick gold coating from Agar Scientific were used to deposit the free-standing nanofilms for X-ray photoemission spectroscopy (XPS) measurements. PAN (230,000 g mol⁻¹) powder was obtained from Goodfellow. All solvents used for phase inversion, interfacial polymerization and nanofiltration experiments were purchased from VWR. Commercial membranes DuraMem500 and DuraMem200 manufactured by Evonik were purchased from Sterlitech.