FTIR and SEM were applied to examine the new adsorbent (a Hitachi S-4160 scanning electron microscope). The concentration of metal ions was determined via inductively coupled plasma (ICP-AES) (Varian liberty 150 XL).
The Perkin-Elmer Frontier was applied to take FT-IR spectra. Dimethyl sulfoxide (DMSO) or chloroform (CDCl3) were applied as solvent materials for routine spectra of NMR at ambient temp. on an Avance TM 400 spectrometer. It is important to note that all chemical modifications are stated in ppm δ relative to the trace resonance of protonated chloroform, CDCl3 dimethyl sulfoxide, DMSO, and external 85% aqueous H3PO4, as (δ 7.25 ppm), (δ 77.0 ppm), or (δ 2.50 ppm), (δ 39.51 ppm) and (δ 0.0 ppm), respectively.
A mass spectrum was examined by using a GC Finnigan MAT SSQ-7000 type of mass spectrometer. The progress of the reactions and examination of the compound’s purity was completed. The latter was done via thin Layer Chromatography (TLC) on silica gel-precoated aluminium sheets (Type 60, F 254, Merck, Darmstadt, Germany) with an eluent of petroleum ether (60–80 °C)/ethyl acetate, and the spots were identified by exposure to UV light at a lamp at λ254 nm for several seconds. The chemical names of the synthesized chemicals are designated using the IUPAC nomenclature. Conventional drying and purification processes were utilized.
The Perkin-Elmer Frontier was applied to take FT-IR spectra. Dimethyl sulfoxide (DMSO) or chloroform (CDCl3) were applied as solvent materials for routine spectra of NMR at ambient temp. on an Avance TM 400 spectrometer. It is important to note that all chemical modifications are stated in ppm δ relative to the trace resonance of protonated chloroform, CDCl3 dimethyl sulfoxide, DMSO, and external 85% aqueous H3PO4, as (δ 7.25 ppm), (δ 77.0 ppm), or (δ 2.50 ppm), (δ 39.51 ppm) and (δ 0.0 ppm), respectively.
A mass spectrum was examined by using a GC Finnigan MAT SSQ-7000 type of mass spectrometer. The progress of the reactions and examination of the compound’s purity was completed. The latter was done via thin Layer Chromatography (TLC) on silica gel-precoated aluminium sheets (Type 60, F 254, Merck, Darmstadt, Germany) with an eluent of petroleum ether (60–80 °C)/ethyl acetate, and the spots were identified by exposure to UV light at a lamp at λ254 nm for several seconds. The chemical names of the synthesized chemicals are designated using the IUPAC nomenclature. Conventional drying and purification processes were utilized.