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2 protocols using iron ii sulphate heptahydrate

1

Synthesis and Characterization of Graphene-Based Electrocatalysts

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Natural graphite powder, iron(iii) chloride hexahydrate (FeCl3·6H2O, 97%), iron(ii) sulphate heptahydrate (FeSO4·7H2O, 99%), sodium nitrate (NaNO3, 99%), sodium nitrite (NaNO2, 97%), sodium borohydride (NaBH4, 98%) and potassium permanganate (KMnO4, 99.3%) were received from Alfa Aesar. Sulfanilic acid (C6H7NO3S, 99%), sulfuric acid (H2SO4, 95%), hydrogen peroxide (H2O2, 32%) and hydrochloric acid (HCl, 35%) were procured from Daejung Chemicals, South Korea. Nafion solution (5%) in lower aliphatic alcohols and ammonium hydroxide (NH3OH, 5 M) were procured from Sigma Aldrich. N,N-Dimethylformamide (DMF) was obtained from Duksan reagents, South Korea. Gas diffusion electrodes (40 wt% Pt on XC-72) were procured form NARA Cell Tech, South Korea.
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2

Synthesis of Iron Oxide Nanoparticles

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All materials used were of reagent grade and from commercial sources. Iron (III) sulphate hydrate, iron (II) sulphate heptahydrate (ACS, 99+%), and citric acid (99+%) were purchased from Alfa Aesar (Haverhill, MA, USA). Acetone (AppliChem GmbH, Darmstadt, Germany), ethanol absolute (Carlo Erba Reagents GmbH, Emmendingen, Germany), NH4OH (aq) 25% (Honeywell Fluka, Charlotte, NC, USA), and HCl 1 M (Honeywell Riedl-de-Haën, Charlotte, NC, USA) were used as received. Polyethylene oxide (PEO; Mw, 400,000 g/mol) was from Sigma-Aldrich, Co. (St. Louis, MO, USA), and poloxamer 188 (P188; Lutrol F68) was from BASF (Ludwigshafen, Germany). The water used was purified by reverse osmosis.
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