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3 protocols using poly vinylpyrrolidone

1

Synthesis of Metal-Containing Compounds

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Bi(NO3)3·5H2O (99.999%, Sigma-Aldrich),
NH4VO3 (99%,
Daejung Chemicals) poly(vinylpyrrolidone) (K 30, Daejung Chemicals)
were used as metal precursor salts and utilized as received. H2PtCl6·6H2O (≥37.50%, Sigma-Aldrich),
HAuCl4·3H2O (≥99.9%, Sigma-Aldrich),
AgNO3 (>99%, Sigma-Aldrich), methyl orange (SHOWA),
RhB
(Daejung Chemicals), FTO (TEC 15, WY-GMS) coated glass, and methyl
alcohol (99.8%, Daejung Chemicals) were also used as received. Deionized
(DI) water was used as a solvent in all experiments.
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2

Synthesis of Graphene Oxide-Polyurethane Composite

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Thermoplastic polyurethane was obtained from Townsend Corporation (RE-FLEX585-XU, MW = 25KD). Graphite powder (average particle size of <20 µm), and phosphoric acid (H3PO4) were bought from Sigma-Aldrich. Potassium permanganate (KMnO4 Mw ~158.03, Assay = 99.5%) was purchased from AnalaR®. Sodium hydroxide pellets (NaOH: 98% Analytic-ACS) were purchased from ICON CHEMICAL. Polyvinyl pyrrolidone (PVP of Mw ~40,000 Da), sulfuric acid (H2SO4 Assay 98.5%), Hydrogen peroxide (H2O2; 30%) aqueous solution, and N, N-Dimethyl formamide (DMF) were purchased from DAEJUNG. Chloroacetic acid (C₂H₃C.lO₂: 94.49 g/mol−1) was purchased from Merck, Germany. Deionized water (DI) used in this study was produced through an integrated system of a Milli-Q (Merck Millipore, Ireland). All compounds were of analytical rank and were used exactly as directed.
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3

Synthesis of Tungsten Disulfide Nanostructures

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The raw materials sodium tungstate dehydrates, polyethylene glycol, and thioacetamide were purchased from Sigma-Aldrich (St. Louis, MO, USA). Ammonium molybdate tetrahydrate was from Junsei Chemical Co. (Tokyo, Japan). Polyvinylpyrrolidone (PVP), Selenium powder and anhydrous oxalic acid were provided from Daejung (Daejeon, Korea) and used as received without further treatment.
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