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4 protocols using hydrazine monohydrate

1

Synthesis of Bimetallic Electrocatalysts

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Carbon cloth (CC, HCP331; 0.35 +/−0.02 mm; WizMAC Co. Ltd.), Co(NO3)2·6H2O (≥98%, ACS reagent; Sigma‐Aldrich), FeSO4·7H2O (≥99%; Sigma‐Aldrich), hydrazine monohydrate (80% Assay; Daejung Chemicals), KOH (85% Assay, Extreme pure; Reagents Duksan), anhydrous ethanol (99.5%; Daejung Chemicals), Na2PdCl4 (98%; Sigma‐Aldrich), NaCl (≥99% ACS reagent; Sigma‐Aldrich), Pt—C (20 wt% on carbon black; Alfa Aesar). All chemicals were used as received unless a specific process or purification was mentioned separately.
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2

Synthesis of Te-Doped Carbon Nanotubes

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Hydrazine monohydrate (N2H4·H2O, 80%), ethylene glycol (EG, C2H6O2, 99.5%), sodium hydroxide (NaOH, 98%), tellurium(iv) oxide (TeO2, 99%), ethanol (C2H5OH, 94%), nitric acid (HNO3, 60%), and sulfuric acid (H2SO4, 95%) were purchased from Daejung Chemicals & Metals Co. (Seoul, Korea), PVP (molecular weight (MW) = ∼40 000) was purchased from Sigma-Aldrich (St. Louis, USA). The multi-walled carbon nanotubes used in this study were supplied by Hanwha Nanotech (Seoul, Korea).
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3

Synthesis of Tellurium Oxide Nanoparticles

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Tellurium (IV) dioxide (TeO2, 99%), copper (II) nitrate trihydrate (Cu(NO3)2·3H2O, 99%), L (+)-ascorbic acid (C6H8O6, 99%), hydrazine monohydrate (N2H4·H2O, 80%), and ethylene glycol (EG, C2H6O2, 99.5%) were purchased from Daejung Chemicals & Metals Co (Seoul, Korea). Sodium hydroxide (NaOH, 98%), and PVP, [molecular weight (MW) = ~40,000] were purchased from Sigma Aldrich (St. Louis, USA).
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4

Synthesis of Graphene-Based Composites

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Graphite powder was purchased from Merck and form local graphite company (Ulley, South Australia). Glycerine was purchased from Fischer Scientific. K2S2O8 was purchased from Scharlau span, Hydrazine monohydrate was purchased from Daejung. P2O5, MnSO4.H2O, FeSO4.7H2O and H2O2 were purchased from Riedel-deHaen. Pyrrole was purchased from Sigma Aldrich, NiCl2.6H2O was purchased from United Laboratory Chemicals. While FeCl3.6H2O and polytetrafluoroethylene were purchased from Aldrich. Commercial NaOH, HCl, H2SO4, Ethanol and acetone were used. All chemicals were pure and of analytical grade and were used without further purification.
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