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2 protocols using 6 amino 2 naphthoic acid

1

Characterization of Fluorescent Probes

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6-amino-2-naphthoic acid (ANA), 4-aminobenzoic acid (ABA), 4′-amino-[1,1′-biphenyl]-4-carboxylic acid (ABPA), methylene violet (Bernthsen) (MV), coumarin 343 (C343), β-cyclodextrin (β-CD), cucurbit[7]uril (CB7), citric acid/sodium citrate, sodium dihydrogen phosphate/disodium hydrogen phosphate, boric acid/sodium borate and sodium N-cyclohexyl-3-aminopropanesulfonate (CAPS) were obtained from Sigma Aldrich UK and were of the highest purity available.
5, 6-diamino-naphthalene-1, 3-disulfonic acid (DANDSA) was obtained from Molekula, UK.
4-pyridinium phenolate (4PP) was synthesised and provided by WuXi App Tec (Hong Kong) Ltd. Structure and purity were confirmed by NMR.
The provenances of Brooker's merocyanine (BM), bis-dimethylaminofuchsone (BDF), phenol blue (PB), and 2, 6-dichloro-4-(2, 4, 6-triphenyl-pyridinium-1-yl)-phenolate (ET33) are as stated previously.
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ROW was used throughout this study and had a resistivity of 15MΩcm (checked daily).
Disposable high purity UV-transparent cuvettes (Brand GmbH) with stoppers were used throughout and are described previously.
1 (link)
Disposable four-sided optically transparent fluorescence cuvettes (Brand GmbH) made of the same material as the UV cuvettes, with stoppers, were used to record fluorescence spectra.
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2

Synthesis and Purification of Perovskite Precursors

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All chemicals were used as received without further purification. Lead iodide (PbI 2 ) (99.99 %) was purchased from TCI chemicals, methylammomium iodide (MAI) and methylammonium bromide (MABr) from Dyesol, oleic acid (99.0 %), oleylamine (70 %), methylamine (MA) solution (33% in absolute ethanol), 1-Adamantanecarboxylic acid (ADAC) (99%), dicarboxylic biphenyl-4,4'-dicarboxylic acid (97%), butylamine (≥99%), 1-Adamantylamine (97%), 6-Amino-2-naphthoic acid (90%), and 3-Aminopropylphosphonic acid (98%) were purchased from Sigma-Aldrich. All solvents such as toluene, acetonitrile, methyl acetate and ethyl acetate were anhydrous and were purchased from Sigma-Aldrich.
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