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3 protocols using zinc nitrate hexahydrate

1

Synthesis of Zinc Citrate Nanoparticles

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Zinc nitrate hexahydrate [Zn(NO3)2·6H2O] and sodium citrate dihydrate (HOC(COONa)(CH2COONa)2·2H2O) were obtained from J.T Baker (New Taipei City, Taiwan). Sodium hydroxide (NaOH), silver nitrate (AgNO3), and RhB were received from Sigma Aldrich (New Taipei City, Taiwan). All the chemicals were used without further purification. The chemicals used in this study were of analytical grade, and all the required solutions were prepared using deionized water.
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2

Synthesis of Metal-Organic Framework Materials

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Zinc nitrate hexahydrate (≥99%) was purchased from J.T. Baker (Radnor, PA, USA); 2-methylimidazole (2-MeIM, 99%) and polyacrylonitrile (PAN) (Mw = 150 kDa) were obtained from Sigma-Aldrich (St. Louis, MO, USA); cetyltrimethylammonium bromide (CTAB, 98%) and N, N-dimethylacetamide (DMAc, 99%) were purchased from Alfa Aesar (Sisli-Istanbul, Turkey); methanol (≥99.8%) was purchased from Mallinckrodt Chemicals (Phillipsburg, NJ, USA). All the chemicals were used without further purification.
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3

Synthesis and Characterization of Inorganic Compounds

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l-Histidine hydrochloride monohydrate was purchased from TCI (Tokyo, Japan). Potassium nitrate (>99.0%), silver nitrate (>99.0%), and sodium chloride (>99.0%) were purchased from Sigma-Aldrich (St. Louis, MO, USA). Copper nitrate trihydrate (>99.0%), lead nitrate (>99.0%), and sodium bromide (99.5%) were purchased from Acros (Morris Plains, NJ, USA). Magnesium nitrate hexahydrate (>98.0%) and sodium iodide (>99.0%) were procured from SHOWA (Tokyo, Japan). Cobalt chloride (97.0%), iron chloride (98.0%), and mercury chloride (>98.0%) were obtained from Alfa Aesar (Heysham, England). Calcium nitrate tetrahydrate (>99.0%) and manganese chloride dehydrate (>99.0%) were purchased from Merck (Kenilworth, NJ, USA). Monobasic, dibasic, and tribasic sodium salts of phosphate, phosphoric acid (85.0%), sodium hydroxide (98.0%), and zinc nitrate hexahydrate (>99.0%) were obtained from J.T. Baker (Center Valley, PA, USA). Ultrapure water (18.2 MΩ cm) from a Milli-Q system (Millipore, Billerica, MA, USA) was used to prepare all solutions.
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