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2 protocols using 1 2 4 5 tetraaminobenzene tetrahydrochloride

1

Synthesis of BBL Polymer for Electronics

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Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS, Clevios PH1000) was purchased from Heraeus Holding. Naphthalenetetracarboxylic dianhydride (NDA), 1,2,4,5-tetraaminobenzene tetrahydrochloride (TABH), poly(phosphoric acid) (PPA), methanesulfonic acid (MSA), chloroform, 1,2-dichlorobenzene, ethylene glycol, (3-glycidyloxypropyl)trimethoxysilane and 4-dodecylbenzenesulfonic acid were purchased from Sigma-Aldrich. BBL (η = 6.3 dl g−1 in MSA at 30 °C, Mw = 35 kDa) was made by polycondensation of NDA and TABH in PPA at elevated temperatures17 (link),31 (link).
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2

Synthesis of Expandable Graphite Nanomaterials

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Expandable graphite (~300 μm) was purchased from Nanjing Xianfeng Nano Material Technology Co., Ltd. Hydrochloric acid (HCl) (~12 mol L -1 ), potassium permanganate (KMnO 4 ) (≥99.5%), and sulfuric acid (H 2 SO 4 ) (~98%) were purchased from Jiangsu Qiangsheng Functional Chemical Co., Ltd. Hydrogen peroxide (H 2 O 2 ) (30%) was purchased from Shanghai Lingfeng Chemical Reagent Co., Ltd. Potassium persulfate (K 2 S 2 O 8 ) and ethanol (≥99.7%) were purchased from Sinopharm Chemical Reagent Co., Ltd. Phosphorus pentoxide (P 2 O 5 ) was purchased from Energy Chemical Co., Ltd. Aqueous hydroiodic acid (HI, 57 wt%) was purchased from Adamas-Beta. 1,2,4,5-tetraaminobenzene tetrahydrochloride was obtained from Sigma Aldrich. Ultrapure water was collected using a Direct-Q3 ultraviolet (UV) system.
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