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4 protocols using molybdenum trioxide

1

Quantifying Chromium in Plants via ICP-MS

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All chemicals were of analytical reagent grade. Deionized water (18.2 MΩ cm, Labconco, USA), LC-MS-grade methanol, and acetonitrile (MeCN) from Sigma (Milwaukee, USA) were used throughout.
The following Sigma-Aldrich reagents were used: potassium dichromate (Cr(VI)), formic acid, nitric acid, hydrogen peroxide, and sodium hypochlorite. Stock standard solution of chromium (1000 mg/L) was from Sigma and inductively coupled plasma mass spectrometry (ICP-MS) internal standard mix was from Agilent Technologies.
Hoagland's nutrient solution containing calcium nitrate 0.35 mM, calcium chloride 2.1 mM, magnesium sulfate 0.91 mM, monobasic potassium phosphate 0.97 mM, potassium nitrate 1.22 mM, boric acid 23 μM, manganese chloride 3.9 μM, molybdenum trioxide 23 μM, ferric nitrate 10 μM, zinc nitrate 0.6 μM, and copper sulfate 0.44 μM, pH 5.8, was prepared from Sigma reagents [22 ].
Sunflower seeds (Helianthus annuus L.) were purchased at a local garden market as a product of Vita company, distributed in Mexico by Rancho de Molinos, S.A. de C.V.
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2

Perovskite Nanocrystal Synthesis and Characterization

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Cesium carbonate (Cs2CO3, 99 %), Lead(II) bromide (PbBr2, ≥98 %), lead(II) iodide (PbI2, 99.999 %), lead(II) Chloride (PbCl2, 98 %), 1-octadecene (ODE, 90 %), oleic acid (OA, 95 %), oleylamine (OAm), hexane anhydrous (95 %), toluene anhydrous (99.8 %), isobornyl acrylate, dipentaerythritol penta-/hexa-acrylate, diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, IGEPAL 520, IGEPAL 630, diethylene glycol (99 %), triethylene glycol (99 %), glycerol (≥99 %), propylene glycol monoether acetate (PGMEA, ≥9.5), and molybdenum trioxide (MoO3, 99.97 %) from Sigma-Aldrich were used without additional purification. N,N-bis(naphthalen-1-yl)-N,Nbis(phenyl)benzidine (NPB), tris(4-carbazoyl-9-ylphenyl)amine (TCTA), N,N′-dicarbazolyl-3,5-benzene (mCP), bis[2-(4,6-difluoro -phenyl)pyridinato-C2,N](picolinato)iridium(III) (FIrpic), 2,2,2′′- (1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBI), and lithium fluoride (LiF) (1 nm) were purchased from OSM. Aluminum (Al) and silver (Ag) were obtained from TASCO. Indium-tin oxide (ITO) was purchased from GUNZE [6] , [21] .
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3

Synthesis of Halide Perovskite Precursors

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Cesium bromide (CsBr, 99.999%), rubidium bromide (RbBr, 99.6%), lead bromide (PbBr2, 99.999%), lead chloride (PbCl2, 99.999%), lead iodide (PbI2, 99.999%), molybdenum trioxide (MoO3, ≥99.5%), 1,3,5-tris(bromomethyl)−2,4,6-triethylbenzene (TBTB, 97%), chlorobenzene (C6H5Cl, 99.8%) and dimethyl sulfoxide (DMSO, ≥99.9%) were purchased from Sigma Aldrich. 1,1-Bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC, >99.5%) and 1,4,5,8,9,11-Hexaazatriphenylenehexacarbonitrile (HAT-CN, >99%) were purchased from Ossila. All materials were used as received without further purification.
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4

Anticoagulant Assay Protocol

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Sodium nitrate, calcium chloride dehydrates, magnesium sulfate heptahydrate, potassium phosphate, monopotassium phosphate, sodium chloride, boric acid, EDTA, zinc sulfate heptahydrate, chloride tetrahydrate, molybdenum trioxide, copper (II) sulfate pentahydrate and cobalt (II) nitrate hexahydrate were obtained from Sigma-Aldrich, Dorset, UK. 2,2′-azino-bis(3-ethylbenzthiazoline-6-sulfonate) (ABTS), 1,1-diphenyl-2 picrylhydrazyl (DPPH), were purchased from Sigma Chemical Co. (St. Louis, MO, USA). Commercial kits for aPTT and PT tests were purchased from Fisher Scientific, Canada. Heparin sodium was obtained from Hi-Media Laboratories, Mumbai, India.
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