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2 protocols using lauryl methacrylate lma

1

Synthesis of Organic Photofunctional Materials

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ZrCl4, DMF,
acetic acid, 2-aminoterephthalic acid, toluene, chlorodimethylsilane,
10-undecenyl 2-bromoisobutyrate (95%), Karstedt’s catalyst
in xylene (99%), anisole, ethyl 2-bromoisobutyrate, lauryl methacrylate
(LMA, 98%), CuI, CuBr, and N,N,N′,N′,N″-PMDETA
(99%) were purchased from Sigma-Aldrich, Germany. Naphthalene (Nap),
fluorine (Flu), acenaphthylene (Ace), anthracene (Ant), phenanthrene
(Phe), and pyrene (Pyr) were purchased from Merck (Darmstadt, Germany).
CuBr (98%) was agitated in glacial acetic acid for 12 h before being
filtered and washed with ethanol, followed by drying under vacuum.
The purified CuBr powder was stored in a desiccator. LMA was dissolved
in tetrahydrofuran (THF); then, it was passed through a silica gel
column to eliminate the inhibitor, and then, THF was removed under
high vacuum.
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2

Monolithic Column-Based Coenzyme Q10 Analysis

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All chemicals were of analytical reagent grade. Ethylenedimethacrylate (EDMA, 99%), acetonitrile (LC-MS grade), and 3-trimethoxysilylpropyl methacrylate (TMSPM, 98%) were purchased from Sigma-Aldrich. 2.2′-Azobisizobutyronitrile (AIBN) and methanol (LC-MS grade) were purchased from Merck A.G (Darmstadt, Germany). A reducing union (1/16′ to 360 μm) SS, for FS tubing (S/N: L-P112240) from VICI Valco was used for the capillary connection between the monolithic column and the flow cell of detector. A TSP-050375-fused silica capillary with a 50 μm i.d. and a 363 μm o.d. (Lot: BUHT02A) was obtained from BGB Analytik. An amount of 2- propanol was purchased from Carlo Erba (for HPLC, isocratic grade). Ethanol (LC grade) was purchased from Isolab. Lauryl methacrylate (LMA, Lot: MKCL9070) and poly (ethyleneglycol) (PEG, Lot: BCCD8009) were supplied from Sigma-Aldrich. Coenzyme Q10 (≥98, HPLC, Lot: SLCF9505) was purchased from Sigma-Aldrich, and sodium chloride (NaCI) was supplied from Merck.
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