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2 protocols using 4 vinylaniline

1

Synthesis of Functional Polymeric Materials

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Unless otherwise indicated, all solvents
were purchased from commercial sources and were used without further
purification. 3,4-Diethoxycyclobut-3-ene-1,2-dione (95%, ABCR), zinc
trifluoromethanesulfonate (98%, Sigma-Aldrich), 4-vinylaniline (97%,
Sigma-Aldrich), 2-aminoethyl methacrylate hydrochloride (90%, Sigma-Aldrich), N,N-diisopropylethylamine (DIPEA, >99%,
Sigma-Aldrich), N,N-dimethylacrylamide
(DMAAm, 99%, Sigma-Aldrich), ethylene glycol dimethacrylate (EGDMA,
98%, Sigma-Aldrich), 2,2′-azobis(2-methylpropionitrile) (AIBN,
98%, Sigma-Aldrich), tetrabutylammonium fluoride hydrate ([Bu4N]+[F], 98%, ABCR), tetrabutylammonium
chloride ([Bu4N]+[Cl], >97%,
Sigma-Aldrich), tetrabutylammonium bromide ([Bu4N]+[Br], >98%, Sigma-Aldrich), tetrabutylammonium
iodide ([Bu4N]+[I], 98%,
Sigma-Aldrich), and tetrabutylammonium acetate ([Bu4N]+[AcO], 95%, ABCR) were used as received.
AIBN was recrystallized from methanol prior to use and stored below
5 °C. To remove the residual inhibitor, the main monomer DMAAm
was destabilized via a short column of basic alumina prior use.
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2

Synthesis of Organolead Halide Perovskites

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MilliQ water was obtained using an IQ 7000 purifying system. Ethanol absolute (analytical grade), tetrahydrofuran anhydrous 99.99 % (THF), diethyl ether (puriss. p.a. ACS reagent dried 0.05 % GC 0.0075 % water) and hexane (HPLC grade) were purchased from Scharlau. 4-Vinylaniline (97%), tetradecane (≥ 99 %), aqueous hydriodic acid (HI, 55 wt%), lead iodide (99.999 % trace metals basis, PbI2), benzoyl peroxide (75%), lead bromide (99.999 % trace metals basis, PbBr2), potassium iodide (99.5%, KI) and deuterium oxide (D2O) were purchased from Sigma Aldrich. All solvents and reagents were used without further purification.
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