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Kf 6011

Manufactured by Shin-Etsu Chemical

KF-6011 is a laboratory equipment product manufactured by Shin-Etsu Chemical. It is designed for moisture content determination using the Karl Fischer titration method. The KF-6011 provides precise and reliable measurements of water content in various sample types.

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12 protocols using kf 6011

1

Novel Hair Wax Formulation

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Example 20

Hair Wax

A cosmetic composition was prepared by step A of heating ingredients 10 to 16 at 80° C. and mixing until uniform, step B of heating ingredients 1 to 9 at 90° C. and mixing until uniform, step C of adding B to A, emulsifying, and cooling down to room temperature, and step D of adding ingredients 17 and 18 to C and mixing until uniform, to form a hair wax.

IngredientsAmount (%)
1. 80% isododecane solution of Polymer II1
2. Methyltrimethicone *110
3. Candelilla wax13
4. Microcrystalline wax8
5. POE glyceryl isostearate2
6. Glycerol monostearate3
7. Polyether-modified silicone *22
8. Stearic acid2
9. 2-ethylhexyl p-methoxycinnamate0.1
10. Propylene glycol6
11. 1,3-butylene glycol6
12. Carboxyvinyl polymer0.3
13. Methyl p-hydroxybenzoate0.2
14. Phenoxyethanol0.3
15. Trisodium edetateproper
16. Purified waterbalance
17. Potassium hydroxide (10% solution)proper
18. Perfumeproper
100
*1 Methyltrimethicone: TMF-1.5 by Shin-Etsu Chemical Co., Ltd.
*2 Polyether-modified silicone: KF-6011 by Shin-Etsu Chemical Co., Ltd.

The hair wax was less squeaking, retentive and hair style lasting.

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2

Emulsified Silicone-Based Skin Cream

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Example 11

TABLE 5
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 45.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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3

Formulation and Evaluation of Cuticle Coat

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Example 68

Preparation and Evaluation of a Cuticle Coat

A cuticle coat having the composition as shown in the following Table 23 was prepared, and its properties in use was evaluated. The preparation method was as follows. The cuticle coat obtained lightly spread, suppresses dry feeling of hair and gave gloss and smoothness on hair.

(Preparation Method)

  • Step A: Components 1 to 3 were homogeneously mixed.
  • Step B: Components 4 to 10 were homogeneously mixed.
  • Step C: The mixture obtained in step A was gradually added to the mixture obtained in step B while stirring to be emulsified to obtain a cuticle coat.

TABLE 23
Example(%)
Component68
1. Copolymer (A) of Example (6)1.0
2. Silicone gum dissolved product (note 82)40.0
3. Decamethylcyclopentasiloxane42.0
4. Polyether-modified silicone (note 83)3.0
5. Polyether modified silicone (note 84)2.0
6. PEG-40 hydrogenated cured castor oil1.0
7. Alcohol5.0
8. PreservativeProper
amount
9. PerfumeProper
amount
10. Purified water6.0
(Note 82)
KF-9028 manufactured by Shin-Etsu Chemical Co., Ltd.
(Note 83)
KF-6011 manufactured by Shin-Etsu Chemical Co., Ltd.
(Note 84)
KF-6013 manufactured by Shin-Etsu Chemical Co., Ltd.

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4

Transparent Cleansing Lotion Formulation and Evaluation

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Example 67

Preparation and Evaluation of a Transparent Cleansing Lotion

A transparent cleansing lotion having the composition as shown in the following Table 22, and its properties in use were evaluated. The preparation method was as follows. The transparent cleansing lotion obtained lightly spread, had moist feeling and gave high cleansing effect.

(Preparation Method)

  • Step A: Components 1 to 4 were homogeneously mixed.
  • Step B: Components 4 to 10 were homogeneously mixed.
  • Step C: The mixture obtained in step A was gradually added to the mixture obtained in step B while stirring to be emulsified to obtain a transparent cleansing lotion.

TABLE 22
Example(%)
Component67
1. Decamethylcyclopentasiloxane53.8
2. Copolymer (A) of Example (5)2.0
3. Neopentyl glycol dioctanoate6.0
4. Silica0.2
5. 1,3-butylene glycol5.0
6. Glycerin6.0
7. Polyether modified silicone (note 80)5.0
8. Polyether-modified silicone (note 81)3.0
9. PEG-60 hydrogenated castor oil2.0
10. Purified water17.0
(Note 80)
KF-6011 manufactured by Shin-Etsu Chemical Co., Ltd.
(Note 81)
KF-6013 manufactured by Shin-Etsu Chemical Co., Ltd.

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5

Formulating a Cosmetic Cream with Silicone Components

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Example 12

TABLE 6
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 55.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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6

Oil-in-Water Cream Formulation

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Example 7

(Component)Weight(%)
1.Ethanol15.0
2.Propylene glycol3.0
3.Polyether-modified silicone(Note 1)0.5
4.Glyceryl trioctanoate, IOB = 0.352.0
5.Dimethylpolysiloxane, 6 mm2/sec2.0
6.Treated powder 113.0
7.Hybrid silicone composite powder(Note 2)5.0
8.Carboxyvinyl polymer, aqueous 1% solution20.0
9.Xanthan gum, aqueous 2% solution6.0
10.Triethanolamine0.2
11.Antiseptic0.1
12.Perfume0.1
13.Purified water60.6
(Note 1)
Polyether-modified silicone: KF-6011, ex Shin-Etsu Chemical Co., Ltd.
(Note 2)
Hybrid silicone composite powder: KSP-100, ex Shin-Etsu Chemical Co., Ltd.
Preparation Method
A: Components 1 to 7 were mixed.
B: Components 8 to 13 were mixed to dissolve together.
C: The mixture obtained in the step A was added to the mixture obtained in the step B, stirred to emulsify.

The oil-in-water cream comprising the present treated powder had no stickiness or oiliness, gave moist, fresh, and refreshing feeling. In addition, the durability of makeup was excellent and the makeup did not change with time or in temperature change and, therefore, the stability was excellent.

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7

Formulation and Characterization of Antiperspirant

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Example 17

TABLE 12
Components% by mass
1.polyether-modified silicon (*1)0.5
2.hydroxy-aluminum chloride3.0
3.talc5.0
4.ethyl alcohol15.0
5.hydroxyethyl cellulose2.0
6.Water absorbing polymer particle 55.0
7.water69.5
(*1) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(Production Method)
A: components 1 to 7 were mixed.
B: the mixture obtained by A was fed in a roll-on container.

The antiperspirant composition thus obtained gave light and smooth touch after it was dried without causing stickiness in application thereof, and was excellent in usability.

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8

Cosmetic Cream Formulation and Evaluation

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Example 10

TABLE 4
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 35.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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9

Silicone-based Cosmetic Cream Formulation

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Example 13

TABLE 7
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 65.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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10

Cosmetic Cream Formulation and Characterization

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Example 8

TABLE 2
Components% by mass
1.crosslinked dimethylpolysiloxane (*1)10.0
2.isotridecyl isononanate5.0
3.decamethylcyclopolysiloxane25.0
4.polyether co-modified silicone (*2)0.5
5.dipropylene glycol6.0
6.glycerin5.0
7.methyl cellulose (*3)5.0
8.polyacrylamide-type emulsifier (*4)2.0
9.antisepticDosage
10.perfumeDosage
11.Water absorbing polymer particle 15.0
12.waterResidue
(*1) KSG-15: manufactured by Shin-Etsu Chemical Co., Ltd.
(*2) KF-6011: manufactured by Shin-Etsu Chemical Co., Ltd.
(*3) METOLOSE SM-4000: manufactured by Shin-Etsu Chemical Co., Ltd.
(*4) SEPIGEL 305; manufactured by SEPIC
(Production Method)
A: components 5 to 12 were mixed.
B: components 1 to 4 were mixed and dissolved, and added to the mixture obtained by A, which was stirred and emulsified.

The cream thus obtained was lightly spreadable and gave fresh and refreshing feel in use without stickiness and greasy touch.

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