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5 protocols using lead ii bromide

1

Fabrication of Perovskite Solar Cells

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Formamidinium iodide (FAI, >99.5%) was obtained from Greatcell Solar Australia Pty., Ltd. Dimethylsulfoxide (DMSO, 99.7%) and N,N-dimethylformamide (DMF, 99.8%) were purchased from Acros Organics. Chlorobenzene (99.8%), titanium(iv) isopropoxide (TTIP, 99.999%) and cesium iodide (CsI, 99.999%) were obtained from Sigma-Aldrich. Lead(ii) iodide (PbI2, 99.99%) and lead(ii) bromide (PbBr2, 99%) were purchased from Tokyo Chemical Industry (TCI). All chemicals were used as received without further purification.
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2

Perovskite Nanocrystal Synthesis

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Cesium carbonate (Cs2CO3, reagent Plus, 99%), lead(II) iodide (PbI2, 99.999% trace
metals basis), toluene (anhydrous, 99.5%),
octadecene (ODE, technical grade, 90%), oleylamine (OLA, 70%), and
oleic acid (OA, 90%) were purchased from Sigma-Aldrich, and lead(II)
bromide (PbBr2, for the perovskite precursor) was purchased
from Tokyo Chemical Industry. All chemicals were used without any
further purification.
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3

Perovskite Solar Cell Materials Synthesis

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Methylammonium iodide (CH3NH3I (MAI), 99.99%), methylammonium bromide (CH3NH3Br (MABr), 99.99%) and formamidinium iodide (CH(NH2)2I (FAI), 99.99%), and formamidinium bromide (CH(NH2)2Br (FABr), 99.99%) were purchased from Hangzhou Perov Optoelectronic Technology Co., Ltd. Lead (II) iodide (99.99% metals basis), lead (II) bromide (>98%), cesium bromide (>99%), cesium iodide (>99%), and bathocuproine (>99%) were purchased from Tokyo Chemical Industry Co., Ltd. All other chemicals were purchased from Sigma-Aldrich and used as received.
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4

Synthesis of Perovskite Thin Films via Solution Processing

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Indium nitrate hydrate (In(NO3)3·xH2O, 99.999%) powder, N,N-dimethylacetamide (DMAC, 99.5%) were purchased from Sigma-Aldrich. 2-methoxyethanol (2-ME, 99.3%), acetylacetone (AcAc, 99%) and ammonium hydroxide (NH3·H2O, 28%) were obtained from Alfa Aesar. Formamidinium iodide (FAI, >98.0%), Methylammonium iodide (MAI, >99.0%), Cesium iodide (CsI, >99.0%), Lead (II) iodide (PbI2, 99.99%), Methylammonium bromide (MABr, >99.0%) and Lead(II) bromide (PbBr2, 99.99%) were purchased from Tokyo Chemical Industry Co. Ltd (TCI). Temozolomide (DMSO, 99%), N,N-Dimethylformamide (DMF, 98%) and chlorobenzene (CB, 99.8%) were purchased from J&K Scientific. Dichloromethane (DCM) was obtained from Innochem Science & Technology Co., Ltd. Colorless polyimide (CPI) powder was from Zhejiang OCAs New Materials Co. Ltd. Silicon wafer with 100 nm thick SiO2 layer was obtained from Silicon Valley Microelectronics, Inc. Isopropyl alcohol (AR, 99.7%), acetone (AR, 99.5%) and hydrochloric acid (HCl; AR, 36–38%) were provided by China National Medicines Co. Ltd. (Shanghai, China). Poly(perfluoroalkyl vinyl ether) (CYTOP) was purchased from Asahi glass company (Japan) and consisted of CTL-809M (solute) and CT-Solv.180 (solvent). Polymethyl methacrylate (PMMA, 495 K A2) was purchased from Kayaku Advanced Materials.
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5

Perovskite Solar Cell Fabrication

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Lead(II) iodide (PbI2; 99.99%, trace metals basis) and lead(II) bromide (PbBr2; >98.0%) were purchased from Tokyo Chemical Industry (TCI). Methylammonium chloride (MACl; 98%), cesium iodide (CsI; 99.9%, trace metals basis), anhydrous N, N-dimethylformamide (DMF; 99.8% v/v), anhydrous dimethyl sulfoxide (DMSO, 99% v/v), anhydrous chlorobenzene (99.8%), anhydrous ethyl acetate (99.8%), anhydrous ethanol (ethanol; 99.5% v/v), tin(II) chloride dihydrate (SnCl2·2H2O; 99.999%), hydrochloric acid (HCl; 37% v/v), 4-tert-butylpyridine (tBP), lithium bis-(trifluoromethanesulfonyl) imide (Li-TFSI), acetonitrile (anhydrous; 99.8%), copper(I) thiocyanate (CuSCN; 99%), and diethyl sulfide 98% were purchased from Sigma Aldrich. Propan-2-ol (AR grade) was purchased from RCI labscan. Formamidinium iodide (FAI; >99.99%), formamidinium bromide (FABr; >99.99%), and methylammonium bromide (MABr; >99.99%), and TEC15 FTO glass plate (2.2 mm thick) were purchased from Greatcell solar. TEC15 ITO glass (1.1 mm thick) was purchased from Luminescence Technology Corp. Tin(IV) oxide (15wt% in H2O colloidal dispersion) and ferrocene (99%) were purchased from Alfa Aesar. 2,20,7,70-tetrakis[N,N-bis(4-methoxyphenyl)amino]-9,90-spirobifluorene (spiro-OMeTAD) was purchased from Feiming chemical. Alconox detergent powder was purchased from Alconox. Carbon paste (Jelcon CH-8) was purchased from Jujo chemical.
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