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2 protocols using formalin solution 37 wt

1

Synthesis of Ruthenium-Based Catalysts

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Chemicals and reagents: poly(ethylene oxide)-block-poly(propylene oxide)-block-poly-(ethylene oxide) triblock copolymer Pluronic F127 (Mw = 12 600, PEO106PPO70PEO106), RuCl3·3H2O, phenol, formalin solution (37 wt%), sodium hydroxide, hydrochloric acid, ethanol, and the nitroarenes were purchased from Sinopharm Chemical Reagent Co., Ltd., which were analytical-grade and used as received without purification. All chemicals were used as received without any further purification. Deionizer water was used throughout to prepare all solutions.
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2

Synthesis of Metal Nanoparticles using Pluronic F127

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The poly(ethylene oxide)-block-poly(propylene oxide)-block-poly-(ethylene oxide) triblock copolymer Pluronic F127 (Mw = 12 600 g mol–1, PEO106PPO70PEO106) was purchased from Sigma-Aldrich. Ni(NO3)2·6H2O, Fe(NO3)3·9H2O, Co(NO3)2·6H2O, phenol, formalin solution (37 wt%), sodium hydroxide, hydrochloric acid, ethanol, 1,10-phenanthroline monohydrate (phen), acetylacetone (acac), and nitroarenes were purchased from Sinopharm Chemical Reagent Co., Ltd., which were of analytical grade and used as received without purification. Deionized water was used in all the experiments.
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