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7 protocols using cobalt 2 nitrate hexahydrate co no3 2 6h2o

1

Synthesis of Graphene-Based Electrodes

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H2SO4 (98%), H2O2 (35%), and HCl (5%) were purchased from Dae-Jung (Suwon, Korea). Graphite flakes, NaBH4, nickel (II) nitrate hexahydrate (Ni(NO3)2·6H2O), cobalt (II) nitrate hexahydrate (Co(NO3)2·6H2O), urea, thiourea, ammonium fluoride (NH4F), KOH, N-methyl-2-pyrrolidone (NMP), and polyvinylidene fluoride (PVDF) were purchased from Sigma-Aldrich (Steinheim, Germany). All of these materials were used without any further purification.
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2

Synthesis of Cobalt and Nickel Ferrite Catalysts

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The cobalt ferrite and nickel ferrite catalyst supports were synthetized from the following precursors: cobalt(II) nitrate hexahydrate, Co(NO3)2∙6H2O, MW: 291.03 g/mol (Sigma-Aldrich, Saint Louis, MO 63103, USA); nickel(II) nitrate hexahydrate, Ni(NO3)2∙6H2O, MW: 290.79 g/mol (Thermo Fisher GmbH, D-76870 Kandel, Germany); iron(III) nitrate nonahydrate, Fe(NO3)3∙9H2O (VWR International, Leuven, Belgium); ethylene glycol, HOCH2CH2OH, (VWR Int. Ltd., F-94126 Fontenay-sous-Bois, France); monoethanolamine, NH2CH2CH2OH (Merck KGaA, D-64271 Darmstadt, Germany); and sodium acetate, CH3COONa (ThermoFisher GmbH, D-76870 Kandel, Germany). Palladium(II) nitrate dihydrate, Pd(NO3)2·2H2O (Alfa Aesar Ltd., Ward Hill, MA 01835, USA) was used to deposit Pd onto the ferrite catalyst supports. Nitrogen (purity 4.0, Messer) and hydrogen (purity 4.0, Messer) were used during the experiments. Nitrobenzene (NB, Acros Organics, Morris Plains, NJ 07950, USA) was used as reactant during the catalytic hydrogenation tests. The analytical standards applied (azobenzene, nitrosobenzene, N-methylaniline) were purchased from Sigma-Aldrich Co. (St. Louis, MO 63118, USA).
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3

Photocatalytic Bisphenol-A Degradation

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Bisphenol-A [2,2-bis (4-hydroxyphenyl) propane or BPA] (C15H16O2) was procured from Sigma Aldrich. Titanium dioxide (Degussa P25) was used as catalyst and obtained from Evonik Degussa Corporation, USA. Cobalt (II) Nitrate Hexahydrate [Co (NO3)2.6H2O] and Urea were procured from Sigma Aldrich and were utilized as dopant. Hydrochloric acid (HCL) and sodium hydroxide (NaOH) were purchased from S. D. Fine Chemicals Limited, India and utilized to maintain the pH. For all the tests, distilled water (DW) and methanol were utilized as a solvent.
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4

Synthesis of Plasmonic Nanostructures

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Gold (III) chloride trihydrate (HAuCl4∙3H2O), cysteamine hydrochloride, NaBH4, TBAH, TTIP (Ti[OCH(CH3)2]4), cobalt (II) nitrate hexahydrate (Co(NO3)2∙6H2O), potassium phosphate monobasic, and potassium phosphate dibasic trihydrate were purchased from Sigma-Aldrich (St. Louis, MO, USA). 2-Propanol and isopropanol were obtained from Samchun Pure Chemical Co., Ltd (Pyeongtaek-si, Republic of Korea). ITO-coated glasses (sheet resistance = 10 mΩ cm−2, 10 mm× 37 mm × 0.7 mm Th) were purchased from Taewon Scientific Co., Ltd (Seoul, Republic of Korea).
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5

Cobalt and Nickel Extraction from Nitric Acid

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Cobalt(II) nitrate hexahydrate Co(NO3)2·6H2O (purchased from Sigma-Aldrich, Darmstadt, Germany; purity > 99%) 6 mg/mL and nickel(II) nitrate hexahydrate Ni(NO3)2·6H2O (purchased from Sigma-Aldrich; purity > 99%) 60 mg/mL were dissolved in nitric acid solutions (HNO3 3 M) to form the aqueous phase. The organic phase was prepared by mixing kerosene (Exxsol D80, purchased from Brenntag, Essen, Germany), tributylphosphate [TBP; O=P(OC4H9)3] (purchased from Sigma Aldrich; 97% purity) as modifier at constant volume concentration (5% v/v) and the phosphinic acid Cyanex 272 (purchased from Sigma-Aldrich; purity 90%) as the extractant at different volume concentrations (10–30% v/v). Sodium hydroxide (purchased from Sigma-Aldrich; 98% purity) was used for the pre-neutralization of the organic phase.
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6

Synthesis of Metal-Organic Frameworks

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Benzene-1,4-dicarboxylic acid (H2BDC), benzene-1,3,5-tricarboxylic acid (H3BTC), and cobalt(II) nitrate hexahydrate (Co(NO3)2·6H2O) were purchased from Sigma Aldrich. Ethanol, mEthanol, N,N-dimethyl formamide (DMF), and sodium hydroxide (NaOH) pellets were acquired from Samchun Pure Chemicals, Korea. H2S gas (500 ppm balanced with N2 gas) was procured from Union gas, Korea.
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7

Cobalt-Catalyzed PAN Degradation of SMX

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Polyacrylonitrile (PAN, Mw=150,000) (Sigma-Aldrich), cobalt(II) nitrate hexahydrate (Co(NO 3 ) 2 ×6H 2 O) (Sigma-Aldrich) and Dimethylformamide (DMF) (VWR) were used for the dope solution preparation. Peroxymonosulfate (PMS) (Alfa Aesar) was used as the oxidant and sulfamethoxazole (SMX) (Sigma-Aldrich) was chosen as the target organic pollutant in the catalytic degradation process. Glacial acetic acid (C 2 H 4 O 2 ) and methanol (CH 4 O) were provided by Sigma-Aldrich and used for the mobile phase in SMX detection. All chemicals used in the current study were of reagent grade or higher and were used as received.
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