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Cyanomethyl dodecyl trithiocarbonate

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Cyanomethyl dodecyl trithiocarbonate is a chemical compound used in laboratory settings. It is a colorless or pale yellow liquid with a characteristic odor. The compound is commonly used as a reagent in various chemical reactions and analyses.

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Lab products found in correlation

Nipam, by Merck Group (1 mentions) 4 4 azobis 4 cyanovaleric acid acva, by Merck Group (1 mentions) Oegma, by Merck Group (1 mentions) Degma, by Merck Group (1 mentions) N 3 dimethylamino propyl n ethylcarbodiimidehydrochloride edc hcl, by Thermo Fisher Scientific (1 mentions) 2 2 azobisisobutyronitrile aibn, by Merck Group (1 mentions) 1 4 dioxane, by Merck Group (1 mentions) 4 dimethylaminopyridine dmap, by Merck Group (1 mentions) Sodium chloride (nacl), by Carl Roth (1 mentions) Acryloyl chloride, by Thermo Fisher Scientific (1 mentions) Sodium bicarbonate, by Thermo Fisher Scientific (1 mentions) Cdcl3, by Cambridge Isotopes (1 mentions) Methyl acrylate ma, by Merck Group (1 mentions) Trioxane, by Merck Group (1 mentions) Acetic acid, by Cambridge Isotopes (1 mentions) Isobornyl acrylate iba, by Merck Group (1 mentions) Acetic anhydride, by Merck Group (1 mentions) Sodium sulfate, by Merck Group (1 mentions) Azobisisobutyronitrile, by Merck Group (1 mentions) Biphenyl, by Merck Group (1 mentions)

2 protocols using cyanomethyl dodecyl trithiocarbonate

1

Synthesis of Thermoresponsive Polymer Brushes

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The solvents petroleum ether (40–60 °C), diethyl ether, dichloromethane, ethyl acetate and acetone, and the reagents cyanomethyl dodecyl trithiocarbonate, 4,4′-azobis(4-cyanovaleric acid) (ACVA) and 4-dimethylaminopyridine (DMAP) were purchased from Sigma Aldrich and used as received. N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC·HCl) was purchased from Alpha Aesar and used as received. 1,4-Dioxane, and the monomers DEGMA, OEGMA (Mn = 300 g mol–1), nBA and DMA were purchased from Sigma Aldrich and passed through a column of basic alumina prior to use. NIPAM was purchased from Sigma Aldrich and recrystallized from a toluene–hexane mixture prior to use. 2,2′-Azobisisobutyronitrile (AIBN) was purchased from Sigma Aldrich and recrystallized from methanol prior to use. Dialysis membrane (MWCO = 3.5–5 kDa) was purchased from Spectra/Por. The synthesis of N,N-diethylacrylamide,61
2-cyano-2-propyl dodecyl trithiocarbonate,62
4-cyano-4-(((ethylthio)carbonothioyl)thio) pentanoic acid63
have been described previously in the literature.
Blackman L.D., Gibson M.I, & O'Reilly R.K. (2016). Probing the causes of thermal hysteresis using tunable N agg micelles with linear and brush-like thermoresponsive coronas †Electronic supplementary information (ESI) available: NMR spectra of small molecules and polymers, SEC chromatograms of the polymers, DLS, SLS and turbidimetry data for the micelles, a discussion of the chain density of micelles 11–15, additional calculations regarding the core composition of polymers 1–5 and definitions and calculations related to the light scattering data. See DOI: 10.1039/c6py01191h Click here for additional data file.. Polymer Chemistry, 8(1), 233-244.
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2

Synthesis and Purification of Polymeric Reagents

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Azobisisobutyronitrile
(AIBN, Sigma-Aldrich) was recrystallized from methanol prior to use.
Isobornyl acrylate (IBA; technical, Sigma-Aldrich) and lauryl acrylate
(LA; >98%, TCI) were passed over a basic alumina column prior to
use
to remove the stabilizer. Methyl acrylate (MA; 99%, Sigma-Aldrich)
was distilled prior to use. Pyridine, dichloromethane (DCM), and triethylamine
were distilled over calcium hydride (CaH2) prior to use.
Cyanomethyl dodecyl trithiocarbonate (CDT) was synthesized according
to a procedure mentioned in the literature.44 (link) 2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT;
98%, Sigma-Aldrich), trioxane (≥99%, Sigma-Aldrich), biphenyl
(>99%, Sigma-Aldrich), acetophenone (AP; 99%, Sigma-Aldrich), sodium
sulfate (≥99%, Sigma-Aldrich), acetic anhydride (≥99%,
Sigma-Aldrich), trans-2-[3-(4-tert-butylphenyl)-2-methyl-2-propenylidene]-malononitrile (DCTB; Sigma-Aldrich,
>98%), potassium trifluoroacetate (KTFA; Sigma-Aldrich, 98%), acryloyl
chloride (96%, Alfa Aesar), furfuryl alcohol (≥98%, Fischer
Scientific), hydrogen chloride (HCl; 37% solution in H2O, Acros Organics), sodium bicarbonate (>99%, Acros organics),
sodium
chloride (≥99.8%, Roth), tert-butyl methylether
(TBME; 99.9%), acetic acid (AcOH; 99.7%), and CDCl3 (99.8%,
Cambridge Isotope Laboratories) were used as received. All other solvents
were obtained from Biosolve and were used as received.
Stouten J., Vanpoucke D.E., Van Assche G, & Bernaerts K.V. (2020). UV-Curable Biobased Polyacrylates Based on a Multifunctional Monomer Derived from Furfural. Macromolecules, 53(4), 1388-1404.
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