All reagents were used as purchased without further purification.
Potassium tetrachloroplatinate(II) (K
2PtCl
4, 98%),
sodium tetrachloropalladate(II) (Na
2PdCl
4, 98%),
sodium hexachlororhodate(III) (Na
3RhCl
6), ruthenium(III) chloride hydrate (RuCl
3·xH
2O, 99.98% trace metals basis), palladium(II) chloride (PdCl
2, ≥99.9%), copper(II) chloride dihydrate (CuCl
2·2H
2O, ≥99.0%), nickel(II) chloride hexahydrate (NiCl
2·6H
2O, ≥97%), cobalt(II) chloride hexahydrate (CoCl
2·6H
2O, ≥97%),
sodium molybdate dihydrate (Na
2MoO
4·2H
2O, ≥99%),
L-AA (99%),
dimethylamine borane (97%),
hydrazine monohydrate (N
2H
4·H
2O, N
2H
4 64–65%, reagent grade, 98%), and
Nafion™ perfluorinated resin solution (5 wt% in mixture of lower aliphatic alcohols and water, contains 45% water) were purchased from Sigma Aldrich. The block copolymers, polystyrene-
b-poly(ethylene oxide) (PS
5000-
b-PEO
2200), poly(ethylene oxide)-
b-poly(methyl methacrylate) (PEO-
b-PMMA) with different molecular weights of PMMA blocks, including PEO
10000-
b-PMMA
5500, PEO
10500-
b-PMMA
18000 and PEO
10500-
b-PMMA
22000 (the subscript numbers indicate the average molecular weight (g mol
–1) of the corresponding blocks), were obtained from Polymer Source. DMF,
Tetrahydrofuran (THF), and
acetone were purchased from Nacalai Tesque, Inc.
Kang Y., Cretu O., Kikkawa J., Kimoto K., Nara H., Nugraha A.S., Kawamoto H., Eguchi M., Liao T., Sun Z., Asahi T, & Yamauchi Y. (2023). Mesoporous multimetallic nanospheres with exposed highly entropic alloy sites. Nature Communications, 14, 4182.