Optical absorption
spectra were collected on a Varian Cary 300 UV–vis absorption
spectrophotometer, while PL spectra were recorded by a Varian Cary
Eclipse spectrophotometer using an excitation wavelength at 370 nm
for all of the samples. The NC solutions were diluted in toluene in
quartz cuvettes (path length = 1 cm) to a maximum optical density
below 1.0, to minimize self-absorption effects. The time-resolved
PL measurements were performed on an Edinburgh
FLS900 fluorescence
spectrometer equipped with a time-correlated single photon counting
unit coupled with an Edinburgh Instruments
EPL-510 pulsed laser diodes
(λ
exc = 372 nm, pulse width = 68.8 ps, and λ
exc = 508.2 nm, pulse width = 177.0 ps). Data analysis was
carried out using DecayFit software.
Livakas N., Toso S., Ivanov Y.P., Das T., Chakraborty S., Divitini G, & Manna L. (2023). CsPbCl3 → CsPbI3 Exchange in Perovskite Nanocrystals Proceeds through a Jump-the-Gap Reaction Mechanism. Journal of the American Chemical Society, 145(37), 20442-20450.