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Benzene 1 4 diboronicacid

Manufactured by Apollo Scientific
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Benzene-1,4-diboronicacid is a chemical compound with the formula C6H8B2O4. It is a white crystalline solid that is used as a reagent in organic chemistry and as a building block for certain types of materials.

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Lab products found in correlation

1 4 butanediol bis thioglycolate dithiol dt, by Tokyo Chemical Industry (2 mentions) Dichloromethane dcm, by Avantor (1 mentions) 1 thioglycerol, by Merck Group (1 mentions) 1 ethyl 3 methylimidazolium trifluoromethanesulfonate emim triflate, by Merck Group (1 mentions) Magnesium sulfate heptahydrate mgso4 7h2o, by Thermo Fisher Scientific (1 mentions) Triethylamine, by Merck Group (1 mentions) Poly ethylene glycol diacrylate, by Merck Group (1 mentions) 2 9 oxoxanthen 2 yl propionic acid 1 5 7 triazabicyclo 4.4.0 dec 5 ene salt, by Tokyo Chemical Industry (1 mentions)

2 protocols using benzene 1 4 diboronicacid

1

Copolymer Synthesis and Characterization

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The copolymer of poly(epichlorohydrin) and
PEO (Hydrin C2000XL, Mw = 8.7 × 106 g·mol–1) is obtained from Zeon chemicals (1H NMR
spectrum in Figure S1). Benzene-1,4-diboronic
acid was purchased from Apollo Scientific. Lithium bis(trifluoromethanesulfonyl)imide
(LiTFSI) was purchased from Solvionic. 1,4-Butanediol bis(thioglycolate)
(dithiol, DT) and heptane were purchased from TCI Chemicals. Darocur
1173 (2-Hydroxy-2-methylpropiophenone), 1-thioglycerol, PEG methyl
ether thiol (PEGSH) with an average Mn of 800 g·mol–1, and 1-decanethiol 99% (C10SH) were purchased from Sigma-Aldrich.
Finally, dimethylformamide (DMF), 1-allylimidazole, and magnesium
sulfate heptahydrate (MgSO4·7H2O) were
purchased from Acros-Organics. Dichloromethane (DCM) was acquired
from VWR Chemicals.
All chemicals were used as received without
further purification.
Li F., Nguyen G.T., Vancaeyzeele C., Vidal F, & Plesse C. (2022). Healable Ionoelastomer Designed from Polymeric Ionic Liquid and Vitrimer Chemistry. ACS Applied Polymer Materials, 5(1), 529-541.
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2

Photobase Generator Synthesis Protocol

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The photobase generator (PBG) 2-(9-Oxoxanthen-2-yl)propionic acid 1,5,7-triazabicyclo[4.4.0]dec-5-ene salt, 1,4-Butanediol Bis(thioglycolate) (dithiol, DT), and heptane were purchased from TCI Chemicals (Zwijndrecht, Belgium). Poly(ethylene glycol) diacrylate (PEGDA, Mn = 700 g·mol−1), trimethylolpropane tris(3-mercoptopropianate) (trithiol, TT), triethylamine, 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate (EMIM Triflate), and 1-thioglycerol were purchased from Sigma-Aldrich (De Schnelldorf, Germany). Magnesium sulfate heptahydrate (MgSO4.7H2O) was obtained from Acros Organics (Geel, Belgium). Dichloromethane (DCM) was obtained from VMR Chemicals (Fontenay sous Bois, France). 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM TFSI) was purchased from Solvionic (Toulouse, France). Finally, benzene-1,4-diboronic acid was purchased from Apollo Scientific (Stockport, UK).
Li F., Nguyen G.T., Vancaeyzeele C., Vidal F, & Plesse C. (2022). Photopolymerizable Ionogel with Healable Properties Based on Dioxaborolane Vitrimer Chemistry. Gels, 8(6), 381.
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