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2 protocols using sodium citrate tribasic dihydrate

1

Synthesis and Characterization of Metal Nanoparticles

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Tetrachloroauric acid tetrahydrate (HAuCl4·4H2O), sodium citrate tribasic dihydrate (TSC, 99.0%), silver nitrate (AgNO3, 99.0%), hydrochloric acid (HCl, 36.0−38.0 wt%), L-ascorbic acid (AA, 99.0%), ammonia solution (NH3H2O, 25.0−28.0 wt%), hydrogen peroxide (H2O2, 30.0 wt%), hexamethylenetetramine (HMT, 99.5%), thioacetamide (TAA, 99%), and cadmium acetate (CH3COO)3Cd were purchased from Sinopharm Chemical Reagent Co. Ltd. (Shanghai, China). Sodium borohydride (NaBH4, 99%), hexadecyltrimethylammonium chloride (CTAC, 97%), hexadecyltrimethylammonium bromide (CTAB, 99.0%), sodium iodide (NaI, 99.5%), and potassium chloroplatinite (K2PtCl6, 99.5%) were purchased from Aladdin Reagent. The chemicals were not further purified and were used straight from the original packaging. Deionized (DI) water with a resistivity of 16.8 Ω·cm was used throughout the experiments.
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2

Synthesis of Monodisperse Silica Nanoparticles

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All chemicals were of analytical grade and used as received without further purification. Ferric chloride hexahydrate, ethylene glycol, disodium ethylenediamine tetraacetate, sodium acetate, sodium citrate tribasic dihydrate, ethanol, ammonium hydroxide aqueous solution (28%), tetraethyl orthosilicate (TEOS), silver nitrate, glucose, stannous chloride and hydrochloric acid (37%) were purchased from Sinopharm Chemical Reagent Corporation (Shanghai, P. R. China). Polyvinylpyrrolidone (Mw ∼ 10 000) was obtained from Aladdin Industrial Corporation (Shanghai, P. R. China). Deionized (DI) water was produced by a water purifier system.
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