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5 protocols using 1 tetradecene

1

Analysis of Volatile Organic Compounds

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Authentic standards of 1-hexanol, decanep-cymene, D-limonene, γ-terpinene, 1-octanol, dihydromyrcenol, undecane, nonanal, dodecane, tridecane, 1-tetradecene, tetradecane, pentadecane, hexadecane, heptadecane (all known components of emissions produced by O. smaragdina)20 (link) and hexane were purchased from Sigma-Aldrich. All chemicals were of analytical grade (≥ 98% purity) and were used without further purification.
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2

Synthesis and Characterization of Oleic Acid Nanoparticles

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Oleic acid (99%), sodium oleate (98%) iron chloride hexahydrate [(FeCl3 6H2O), 99%)], oleyl alcohol (85%), 1-tetradecene (>98%), bovine serum albumin (BSA, Cohn fraction V, as a model protein) and glutaraldehyde (25%) were purchased from Sigma Aldrich, USA. EDC [1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride], NHS (N-hydroxysuccinimide), and Alexa Fluor 488 NHS Ester (Succinimidyl Ester) were procured from Thermo-Fisher Scientific, USA. Ethyl alcohol, hexane, chloroform, diethyl ether, hydrochloric acid (HCl), sodium hydroxide (NaOH) and other chemicals were procured from Alfa-Aesar, USA. For cell culture, Dulbecco’s Modified Eagle Medium (DMEM), fetal bovine serum (FBS), trypsin, and penicillin-streptomycin solution were acquired from Fisher Scientific, USA. All chemicals were not further purified. All experiment protocols, methods, and procedures were performed in accordance with the relevant guidelines and regulations of Yale University, USA.
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3

Synthesis and Characterization of PTDMS

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Poly(methylhydrosiloxane) with Mn = 1900 g/mol (ABCR, Karlsruhe, Germany), Karstedt’s catalyst (platinum complex of 1,3-divinyl-1,1,3,3-tetramethyldisiloxane in xylene, Sigma-Aldrich, St. Louis, MO, USA), 1-tetradecene (92%, Sigma-Aldrich, St. Louis, MO, USA), cross-linking agent 1,7-octadiene (98%, Sigma-Aldrich, Munich, Germany), and n-hexane (99%, Chimmed, Podolsk, Russia) were used for the synthesis of PTDMS. Helium (99.995%), methane (99.99%), ethane (99.95%), and n-butane (99.95%) were used for sorption and permeation measurements.
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4

Synthesis of Magnetic Nanoparticles

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All chemicals, iron (III) acetylacetonate >99% (Acros Organics); cobalt (II) acetylacetonate 97% (Sigma); manganese (II) acetylacetonate (Sigma); oleic acid >90% (Sigma); dibenzyl ether >99% (Acros Organics); sodium oleate >82% (Sigma); 1-octadecene >90% (Sigma); poly(maleic anhydridealt-1-octadecene) (Sigma); and 1-tetradecene >92% (Sigma) were used as supplied without further purification.
Note that spherical Fe 3 O 4 particles were purchased from Ocean Nanotech® (see SI).
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5

Authentic standards for O. smaragdina analysis

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Authentic standards of 1-hexanol, decane, p-cymene, D-limonene, γ-terpinene, 1-octanol, dihydromyrcenol, undecane, nonanal, dodecane, tridecane, 1-tetradecene, tetradecane, pentadecane, hexadecane, heptadecane (all known components of emissions produced by O. smaragdina) 20 and hexane were purchased from Sigma-Aldrich. All chemicals were of analytical grade (≥98% purity) and were used without further puri cation.
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