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2 protocols using palladium catalyst

1

Catalytic Hydrogenation of 4-Chlorophenol

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4-chloroPhenol (C6H5ClO, 99+ %) and palladium catalyst (Pd/Al2O3, 1% Pd on alumina powder, with a specific surface area of 150 m2g−1) were purchased from Acros and Alfa Aesar, respectively. Phenol (C6H5OH, 89.6%), sodium sulfate anhydrous (Na2SO4, 99%), sulfuric acid (H2SO4, 98%), sodium bicarbonate (NaHCO3, 99–100%), acetonitrile (99.8+ %), sodium hydroxide (NaOH, 96%), benzoic acid (C7H6O2, 99.9+%), 4-hydroxylbenzoic acid (C7H6O3, 99.9+%), o- Phosphoric acid (H3PO4, 85%), and Acetic Acid (Glacial, HPLC grade) were acquired from Fisher Scientific. Ferrous sulfate (FeSO4.7H2O, pro analysis) was obtained from J.T. Baker Analyzed. palladium catalyst (1% on carbon 4 to 8 mesh), Potassium-hydrogen phthalate (C8H5KO4), HPLC grade water, and methanol were bought from Sigma-Aldrich. The syringe filters with 0.22 μm and 0.45 μm pore sizes were purchased from Millex. Titanium sulfate (TiSO4, 65%) was obtained from GFS Chemicals. All solutions were prepared in de-ionized water (18.2 mΩ.cm), obtained from a Millipore Milli-Q system.
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2

Catalytic Hydrogenation of 4-Chlorophenol

Check if the same lab product or an alternative is used in the 5 most similar protocols
4-chloroPhenol (C6H5ClO, 99+ %) and palladium catalyst (Pd/Al2O3, 1% Pd on alumina powder, with a specific surface area of 150 m2g−1) were purchased from Acros and Alfa Aesar, respectively. Phenol (C6H5OH, 89.6%), sodium sulfate anhydrous (Na2SO4, 99%), sulfuric acid (H2SO4, 98%), sodium bicarbonate (NaHCO3, 99–100%), acetonitrile (99.8+ %), sodium hydroxide (NaOH, 96%), benzoic acid (C7H6O2, 99.9+%), 4-hydroxylbenzoic acid (C7H6O3, 99.9+%), o- Phosphoric acid (H3PO4, 85%), and Acetic Acid (Glacial, HPLC grade) were acquired from Fisher Scientific. Ferrous sulfate (FeSO4.7H2O, pro analysis) was obtained from J.T. Baker Analyzed. palladium catalyst (1% on carbon 4 to 8 mesh), Potassium-hydrogen phthalate (C8H5KO4), HPLC grade water, and methanol were bought from Sigma-Aldrich. The syringe filters with 0.22 μm and 0.45 μm pore sizes were purchased from Millex. Titanium sulfate (TiSO4, 65%) was obtained from GFS Chemicals. All solutions were prepared in de-ionized water (18.2 mΩ.cm), obtained from a Millipore Milli-Q system.
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