Formic acid d2

Manufactured by Merck Group

Sourced in Italy, United States

Formic acid-d2 is a deuterated form of formic acid, a simple carboxylic acid. It is primarily used as a reference compound and an internal standard in analytical and spectroscopic applications.

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Lab products found in correlation

Lithium hydroxide, by Merck Group (2 mentions) Rubidium chloride, by Merck Group (2 mentions) Calcium oxide, by Thermo Fisher Scientific (2 mentions) Barium hydroxide, by Thermo Fisher Scientific (2 mentions) Formic acid, by Thermo Fisher Scientific (2 mentions) Cesium carbonate, by Merck Group (2 mentions) Potassium hydroxide, by Merck Group (2 mentions) Sodium formate, by Merck Group (2 mentions) Deuterium oxide 99.9 d, by Merck Group (1 mentions) Ammonium acetate, by Merck Group (1 mentions) Formic acid, by Merck Group (1 mentions) Acetonitrile, by Merck Group (1 mentions) Gallium metal, by Merck Group (1 mentions) Antimony 3 oxide, by Merck Group (1 mentions)

3 protocols using formic acid d2

Lagrein Wine Analysis by LC-MS

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Liquid
chromatography–mass spectrometry
(LC–MS)-grade solvents (acetonitrile), deuterium oxide 99.9%_D, and additives (formic acid, formic acid-d₂, ammonium acetate, and ammonium acetate-d₇) were obtained from Sigma-Aldrich Srl (Milano, Italy).
Milli-Q water was produced in-house (18.2 MΩ, Sartorius Arium
mini, Sartorius Italy Srl, Varedo, MB, Italy). A sample of Lagrein
wine (2016 harvest) used to develop the SPE method was supplied by
a local winery (Kellerei Bozen, Bolzano, Italy).

Merkytė V., Longo E., Jourdes M., Jouin A., Teissedre P.L, & Boselli E. (2020). High-Performance Liquid Chromatography–Hydrogen/Deuterium Exchange–High-Resolution Mass Spectrometry Partial Identification of a Series of Tetra- and Pentameric Cyclic Procyanidins and Prodelphinidins in Wine Extracts. Journal of Agricultural and Food Chemistry, 68(11), 3312-3321.

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Isotopic Labeling Protocol for Organic Synthesis

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Millipore water was obtained from Milli-Q
water system. Acetonitrile was purchased from PHARMCO-AAPER (Brookfield,
CT). Formic acid (88%), barium hydroxide, and calcium oxide were obtained
from Fisher Scientific (Fair Lawn, NJ). Metal magnesium turnings,
lithium hydroxide, potassium hydroxide, sodium formate, rubidium chloride,
cesium carbonate, and Formic acid-d₂ (95
wt % in D₂O, 98 atom % D) were obtained from Sigma-Aldrich
(Saint Louis, MO). Strontium carbonate was obtained from J. T. Baker
(Avantor, Center Valley, PA). H₂¹⁸O was purchased
from Cambridge Isotope Laboratories (Cambridge, MA). All chemicals
were used without further purification.

Zheng Z., Pavlov J, & Attygalle A.B. (2019). Fortuitous Ion–Molecule Reaction Enables Enumeration of Metal–Hydrogen Bonds Present in Gaseous Ions. ACS Omega, 4(2), 3965-3972.

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Synthesis of Metal Complexes

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Acetonitrile
was purchased from PHARMCO-AAPER
(Brookfield, CT, USA). Formic acid (88%), barium hydroxide, and calcium
oxide were purchased from Fisher Scientific (Fair Lawn, NJ, USA).
Metal magnesium turnings, lithium hydroxide, potassium hydroxide,
sodium formate, rubidium chloride, cesium carbonate, gallium metal,
indium metal, thallium(III) acetate, lead(II) carbonate, antimony(III)
oxide, and Formic acid-d₂ (95 wt % in
D₂O, 98 atom % D) were purchased from Sigma-Aldrich (Saint
Louis, MO, USA). Strontium carbonate was obtained from J.T. Baker
(Avantor, Center Valley, PA). H₂¹⁸O was purchased
from Cambridge Isotope Laboratories (Cambridge, MA). All chemicals
were used without further purification.

Zheng Z., Pavlov J., Wei Y., Zhang Y, & Attygalle A.B. (2018). Periodic Trends Manifested through Gas-Phase Generation of Anions Such as [AlH4]−, [GaH4]−, [InH4]−, [SrH3]−, [BaH3]−, [Ba(0)(η2-O2CH)1]−, [Pb(0)H]−, [Bi(I)H2]−, and Bi– from Formates. ACS Omega, 3(3), 3440-3452.

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