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2 protocols using hydroxymethyledot

1

Fluorinated EDOT Polymer Synthesis

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As described in the Supporting Information, fluorinated 3,4-ethylenedioxythiophene with a
perfluorooctanyl side chain (EDOTF) was custom-synthesized from hydroxymethyl
EDOT (95%) and pentadecafluorooctanoyl chloride (97%) obtained from
Sigma-Aldrich. High-molecular-weight PVC (HMW PVC), bis(2-ethylhexyl)
sebacate (DOS), potassium ionophore I (valinomycin), and tetrahydrofuran
(THF), all Selectophore grade, and anhydrous acetonitrile (ACN; 99.5%)
were purchased from Sigma-Aldrich. KTFAB (97%; Figure S-1) was obtained from Alfa Aesar, and KCl (99.999%,
Suprapur grade) was received from Merck Millipore. All aqueous solutions
were prepared from deionized water (DIW) with a resistivity of 18.2
MΩ cm (ELGA).
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2

Functionalized EDOT-based Conductive Polymers

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Hydroxymethyl EDOT (EDOT-OH, 95%), sodium hydride (NaH, 60% dispersion in mineral oil), trityl chloride (97%), magnesium sulfate (MgSO4), potassium carbonate (K2CO3), triphenylphosphine (PPh3), Amberlite IR-120 resin, sodium methoxide (NaOMe), iron(III) p-toluenesulfonate hexahydrate (technical grade), imidazole (IM, 99%), dimethyl sulfoxide (DMSO), (3-glycidoxypropyl)trimethoxysilane (GOPS, ≥98%), hydrogen tetrachloroaurate(III) hydrate (HAuCl4), trisodium citrate dihydrate (TSC, 99%), DA, AA, UA, and PC were purchased from Sigma–Aldrich. The aqueous PEDOT:PSS solution (Clevios PH1000, PEDOT:PSS ratio = 1:2.5) was purchased from Heraeus with a solid concentration 1.0–1.3 wt%. Tetrahydrofuran (THF), ethyl acetate (EA), hexane, acetone, carbon tetrabromide (CBr4), potassium thioacetate (KSAc), hydrochloric acid (HCl, 37%), and nitric acid (HNO3, 70%) were purchased from Acros Organics. All materials and reagents were used as received without further purification. The aqueous solutions were prepared with deionized (DI) water from a Millipore Milli-Q water treatment system (18.2 MΩ cm−1).
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