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2 protocols using dibutyl sulfide

1

Comprehensive Analysis of Sulfur Compounds

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The studied sulfur compounds: ethanethiol (97%), dimethyl sulfide (99%), 1-propanethiol (99%), thiophene (99%), diethyl sulfide (98%), 1-butanethiol (99%), dimethyl disulfide (99%), ethyl thioacetate (98%), 1-pentanethiol (98%), 2-(methylthio)ethanol (99%), 3-(methylthio)propionaldehyde (96%), dipropyl sulfide (97%), diethyl disulfide (99%), thiophenol (97%), 2-methyltetrahydrothiophene-3-one (97%), 3-thiophenecarboxaldehyde (98%), 3-(methylthio)-1-propanol (98%), 2-thiophenecarboxaldehyde (98%), ethyl 3-(methylthio)propionate (99%), dibutyl sulfide (98%), dipropyl disulfide (98%), and benzothiazole (96%) were purchased from Sigma-Aldrich (St. Louis, MO, USA). Ethanol and sodium chloride were obtained from Chempur (Piekary Slaskie, Poland). EDTA was purchased from Sigma-Aldrich (St. Louis, MO, USA). Distilled water was purified with use of Millipore Simplicity UV purification system (18.2 MΩ·cm, Simplicity Millipore Waters, Milford, MA, USA).
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2

Quantifying Sulfur Compounds in Gasoline

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Dibutylsulfide (DBS, purity 100%), ethyl phenyl sulfide (EPS, 97%), benzothiophene (BT, 97%), methylbenzothiophene (MBT, 96%), dibenzothiophene (DBT, 98%), bromocyclohexane (CXB, 99%) and hexane were purchased from Sigma-Aldrich. Dimethyl sulfide (DMS) in Argon gas standard (2.9±0.3 ppm S, v/v) was obtained from Linde AG (Munich, Germany). CO2:Ar (10:90) and O2:Ar (20:80) were supplied by Air Liquide (Madrid, Spain). Commercial gasoline was obtained from a regular gas station (Asturias, Spain). Certified reference material ERM-EF213, consisting of a real "sulfur-free" gasoline (9.1±0.8 ppm S, w/w) was obtained from BAM (Berlin, Germany).
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