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Azobisisobutyronitrile

Sourced in China

Azobisisobutyronitrile is a chemical compound used as an initiator in free-radical polymerization reactions. It is a solid, white crystalline powder that decomposes at high temperatures to generate free radicals, which can then initiate the polymerization of monomers.

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7 protocols using azobisisobutyronitrile

1

Synthesis and Characterization of Dopamine-Functionalized Nanoparticles

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Dopamine hydrochloride (DA), polyvinylpyrrolidone (PVP, Mr = 8000), azobisisobutyronitrile (AIBN), tris(hydroxymethyl)aminomethane (Tris), polyethyleneimine (PEI, Mr = 70 000), N,N′-carbonyldiimidazole (CDI), 1,6-diaminohexane, LTL were purchased from Macklin Biochemical Co., Ltd (Shanghai, China). AgNO3, NaBH4, CPBA, N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC), N-hydroxy succinimide (NHS), and hydroquinone (HDQ) were obtained from Aladdin Reagent (Shanghai, China). Quercetin (QRT), p-nitrophenol (P-NP) were purchased from Rhawn Chemical Technology (Shanghai, China). Analytical grade sodium phosphate monobasic dihydrate (NaH2PO4), phosphoric acid (H3PO4), styrene (St), methanol (MeOH), ethanol (EtOH), hydrochloric acid (HCl), and sodium hydroxide (NaOH) were purchased from Beijing Chemical Works (Beijing, China). HPLC grade MeOH was purchased from Fisher Scientific (New Jersey, USA).
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2

Synthesis of Polymer-based Adsorbent

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Styrene (St), divinylbenzene (DVB), azobisisobutyronitrile (AIBN), span 80, and ethyl acetate (EAC) were purchased from Shanghai Macklin Biochemical Co., Ltd. Carbon tetrachloride (CTC), dichloromethane (DCM) and trichloromethane were obtained from Chengdu Kelong Chemical Co., Ltd. Hydrochloric acid and toluene were procured from Sinopharm Chemical Reagent Co., Ltd. Petroleum ether and methanol were sourced from Xilong Chemical Co., Ltd. Diesel and corn oil were bought locally in Zhanjiang, and oyster shell powders (OSPs18 (link)) were obtained by self-production. Distilled water was provided by the chemistry laboratory center of the esteemed institution.
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3

Synthesis and Characterization of Poly(butyl acrylate-co-dimethylaminoethyl methacrylate)

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Butyl acrylate (Alfa Aesar, Shanghai, China, purity > 98%), dimethylaminoethyl methacrylate (Macklin, Shanghai, China, purity 99%), acid acrylate (Damao Chemical Reagent Factory, Tianjin, China, analytical reagent), ethyl acetate (Macklin, Shanghai, China, purity 99%), methyl benzoate (Alfa Aesar, Shanghai, China, purity 99%), azobisisobutyronitrile (Macklin, Shanghai, China, purity 98%), polyvinyl alcohol (Macklin, Shanghai, China, PVA-1799), and petroleum ether (Guangzhou Chemical Reagent Factory, Guangzhou, China, analytical reagent).
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4

Synthesis of Functionalized Polymeric Materials

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PVDF (FR 904, >99.5%, Mw 400,000) was purchased from 3F New Materials Co. Ltd., Shanghai, China. Poly(ethylene glycol) methyl ether methacrylate (PEGMA, average Mn 950, contains 300 ppm BHT and 100 ppm MEHQ as inhibitor) was purchased from Aldrich (St. Louis, MO, USA). 1-Vinylimidazole (C5H6N2, 99%), 1-bromobutane (C4H9Br, >99%), N,N-dimethylformamide (DMF, AR) and azobisisobutyronitrile (AIBN, 98%), n-hexadecane (AR, 98%) were supplied by Macklin Biochemical Technology Co., Ltd., Beijing, China. BSA (Mn 67 kDa) was obtained from Aladdin Chemical Co., Ltd., Shanghai, China. Other chemicals utilized in this study were purchased with analytical quality and purified before use. Deionized (DI) water (18.2 MΩ) purified with a Milli-Q system from Millipore (Burlington, MA, USA) was used to prepare all solutions as needed in the work.
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5

Synthesis of Methyl Acrylonitrile Composites

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Methyl acrylonitrile was purchased from Hunan Huateng Pharmaceutical Co., Ltd., China. Methacrylic acid, light magnesium oxide, methyl methacrylate, isopropanol, tert butyl methacrylate, azobisisobutyronitrile, benzoyl peroxide and white carbon black were purchased from Macklin. Short, cut CF was purchased from Shanghai Liso Composite Material Technology Co., Ltd., China.
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6

Synthesis and Characterization of BCG-Loaded Hydrogel

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BCG, chitosan,
glycidyl methacrylate (GMA), ethylene dimethacrylate (EDMA), α-methacrylic
acid (MAA), cyclohexanol, dodecanol, and azobisisobutyronitrile (AIBN)
were purchased from Macklin Reagent (Shanghai, China). Methanol, sodium
dihydrogen phosphate (NaH2PO4), sodium hydrogen
phosphate (Na2HPO4), sodium hydroxide (NaOH),
hydrochloric acid, acetic acid, and acetone were obtained from Jiangsu
Qiangsheng Chemical Co., Ltd. (Changshu, China). The properties of
BCG are shown in Table 1. All other reagents were obtained from various commercial sources
and were of analytical or HPLC grade.
A CARY100 ultraviolet–visible
(UV–vis) spectrophotometer
(Agilent Technologies Inc.) was used for the spectrophotometric analysis.
Scanning electron microscopy (SEM) images were recorded on an S-3400N
analyzer (JEOL Company, Japan). Fourier transform infrared (FTIR)
spectra were performed using an IR200 FT-IR spectrometer (Thermo Corporation).
Thermogravimetric analysis (TGA) was carried out on a Q500 apparatus
(TA) from 30 to 800 °C with a heating rate of 10 °C min–1 under air atmosphere. A B11-2 magnetic stirrer (Shanghai
Sile Instrument Co. Ltd, China) was applied to mix the reaction solutions.
An H1650-W centrifuge (Hunan Xiangyi, China) was used for centrifuging.
A pHS-3E digital pH meter (Shanghai INESA Electron Co. Ltd., China)
was used for pH measurements of sample solutions.
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7

Polymer-Coated Cyclodextrin for Antibacterial Applications

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Methacryloyl chloride (MAC, ≥95%), 1-adamantane methanol (Ada-OH, ≥99%), 2-(dimethylamino) ethyl methacrylate (DMAEMA, ≥99%), triethylamine (Et3N, ≥99.5%), and anisole (≥99.5%) were purchased from Aladdin (Shanghai, China) and used as received. Bromoethane (≥99%), dichloromethane (DCM, ≥99.9%), mono-(6-O-p-methylbenzenesulfonyl)-β-cyclodextrin (≥98%), and tetrahydrofuran (THF, ≥99.5%) were produced by Adamas (Shanghai, China) and used without further treatment. Azo-bis-isobutyronitrile (AIBN, 99%) was supplied by Macklin (Shanghai, China) and recrystallized after being received. HCl (36.5%), NaOH (≥98%), NaCl (≥99.9%), NaBr (≥99%), KI (≥99%), NH4Cl (≥99.5%), NaHCO3 (≥99.5%), and Na2SO4 (≥99%) were obtained from Greagent (Shanghai, China). Ultrapure water with a resistivity of 18.25 MΩ cm−1 was produced by an ultrapure water purifier system (Milli-Q® IQ 70XX), which was used throughout this study. BSA was purchased from Beijing Biosynthesis Biotechnology Co., Ltd. (Beijing, China). E. coli was obtained from Ningbo Mingzhou Biotechnology Co., Ltd. (Ningbo, China).
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