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3 protocols using n methylpyrrole

1

Purification of Pyrrole Derivatives

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Pyrrole (Py, reagent grade,
98%), N-methylPyrrole (MPy, ≥99%), methanol
(MeOH, 95%), sodium hydroxide (NaOH, ≥98%), aluminum oxide
(activated, basic, Brockmann I, standard grade, ∼150 mesh,
58 Å), sodium hydroxide (NaOH, ≥98%), hydrochloric acid
(HCl, 37 wt % aqueous solution), and poly(tetrafluoroethylene) powder
(PTFE, particle diameter: 200 μm) were purchased from Sigma-Aldrich
Co., LLC. N-EthylPyrrole (EPy, >98.0%) was purchased
from Tokyo Chemical Industry Co., Ltd. Each monomer was purified by
passing through a column containing the aluminum oxide before use.
Ferric chloride (FeCl3, 99%) was received from Nacalai
Tesque. Iron(III) chloride hexahydrate (FeCl3·6H2O, assay: min. 99.0%) and sulfuric acid (H2SO4, assay: min. 95.0%) were obtained from Wako Pure Chemistry,
Ltd. pH test paper (046.55) was obtained from As One Co., Ltd. Deionized
water (conductivity, less than 0.06 μS cm–1) was prepared using an MFS RFD240NA GA25A-0715 deionized water producing
apparatus (Advantec, Osaka, Japan).
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2

Synthesis of Iron Oxide Nanoparticles

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com iron oxide (com-Fe3O4) nanopowder 98%
(20–30 nm) was purchased from US-Nano and
used without further purification. PS 280 kDa, nickel nanopowder (<100
nm, com-Ni) 99%, nickel acetate tetrahydrate (Ni-acac), iron(III)
acetylacetonate (Fe-acac), OA, OAm technical grade 70%, 1-octadecene
(1-ODE), TOP, n-methylpyrrole, toluene, methanol
(MeOH), acetone, and chloroform were purchased from Sigma-Aldrich.
The materials were used without further purification.
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3

Synthesis of Polymeric Electrolyte Components

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Glycerol propoxylate (1PO/OH) triacrylate (GPTA, Mn ≈ 428 g mol−1), poly(ethylene glycol) diacrylate (PEGDA, Mn = 700 g mol−1), 2,2-dimethoxy-2-phenylacetophenone (DMPAP, 99%), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI, ≥99%), N-methylpyrrole (99%) and EDOT (97%) were purchased from Sigma-Aldrich. 1H-Pyrrole (99%, extra pure) was bought from ACROS and freshly destilled prior to use. All chemicals were stored and processed under argon atmosphere in a glove box.
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