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Diallylamine

Manufactured by Merck Group
Sourced in Germany

Diallylamine is a chemical compound used as an intermediate in the production of various pharmaceutical and agrochemical products. It serves as a building block for the synthesis of other compounds. The core function of diallylamine is to provide a reactive amine group that can be further modified or incorporated into larger molecules as part of the manufacturing process.

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7 protocols using diallylamine

1

Dichloroacetamide Safeners Characterization

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Dichloroacetamide
safeners
included in this study are AD-67 (technical grade, Nanjing Essence
Fine-Chemical Co., CAS 71526-07-3), benoxacor (99.4%, Sigma-Aldrich,
CAS 98730-04-2), dichlormid (>97.0%, TCI America, CAS 37764-25-3),
and furilazole (99.6%, Fluka, CAS 121776-33-8). For each safener,
a 10 mM stock solution was prepared in HPLC-grade acetonitrile (Fisher
Scientific). Whenever possible, potential hydrolysis products were
either purchased (diallylamine, 99%, Sigma-Aldrich, CAS 124-02-7)
or synthesized [3-methyl-3,4-dihydro-2H-1,4-benzoxazine
and 2-amino-1-(2-furyl)ethanol] as described in the Supporting Information. A full list of reagents is available
in the Supporting Information.
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2

Synthesis of Organometallic Compounds

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Diallylamine, triphenyltin(IV) chloride, diphenyltin(IV) dichloride, MTT salt, and ammonia solution (25%) were purchased from Sigma USA. Whereas, ethyl alcohol, chloroform, and carbon disulphide were supplied by Merck. DMSO was purchased from Fisher Scientific, UK. All reagents and chemicals were used as provided, with no further purification.
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3

Polymer Synthesis and Corrosion Analysis

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Diallylamine (1), N,N-dimethyldodecylamine (4), ammonium persulfate (APS), and 1,6-dibromohexane (5) were purchased from Sigma-Aldrich. Spectra/Por membrane (MWCO: 3.5 kDa) from Spectrum Laboratories Inc. was used to dialyze the synthesized polymers. Mild steel metal samples were obtained from Chrome Contracting Ltd, Riyadh, Saudi Arabia. The composition (wt%) of the mild steel samples was as follows: C (0.21%), Si (0.29%), P (0.06%), Mn (0.49%), S (0.05%), Cu (0.06%), and Fe (balance). The test solution (20% formic acid) was prepared from 98% formic acid purchased from Sigma-Aldrich.
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4

Multifunctional Antimicrobial Polymer Scaffolds

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Polycaprolactone, PCL (MW = 80 kDa), gelatin from bovine skin (CAS 9000-70-8), and tert-butyl acrylate were purchased from Sigma Aldrich, Milan, Italy. Graphite, sulfuric acid, phosphoric acid, hydrogen peroxide, hydrochloric acid, chloroform, methanol, 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), acrylic acid, diallylamine, nutrient broth, nutrient agar, and sodium chloride (NaCl) were purchased from Merck, Darmstadt, Germany. Potassium permanganate was obtained from Bendosen Laboratory Chemicals, Johor Malaysia. The Live/Dead Baclight Bacterial Viability Kit (L7007) was purchased from Thermo Fisher Scientific, Bleiswijk, The Netherlands. The bacterial strains of S.aureus (ATCC 25293) and E.coli (ATCC25922) were received from the Department of Biotechnology, Kulliyah of Science, International Islamic University, Pahang, Malaysia.
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5

Synthesis and Characterization of Phosphonate Esters

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Paraformaldehyde was purchased from Fluka Chemie AG. Diallylamine from Merck Schuchardt OHG, ammonium persulfate (APS), azobisisobutyronitrile (AIBN) and maleic acid from Sigma-Aldrich were used as received. Diallyldimethylammonium chloride (15a) from Sigma-Aldrich, obtained as 65 wt% solution, was freeze-dried and crystallized from methanol/acetone. Phopsphonate ester 1a,15 (link)1b,16 (link) and 5 (ref. 17 (link)) were prepared as described.15–17 (link) For dialysis, Spectra/Por membrane (MWCO: 6000–8000) from Spectrum Laboratories Inc. was utilized.
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6

Synthesis of Anion Exchange Resins

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The anion exchange-resin Lewatit Monoplus MP 800 was provided by Lanxess (Leverkusen, Germany). Double-distilled water, potassium hydroxide, chloroform (≥99%), acetone (≥99%), dichloromethane (≥99%), potassium persulfate, sodium metabisulphite, sodium hydroxide (97%) and N,N’-methylenebisacrylamide were obtained from VWR International GmbH (Darmstadt, Germany). Potassium carbonate (99%), allyl bromide (99%), methanol (99%) and 1,3-bis(4-piperidyl)propane (97+%) were obtained from Alfa Aesar (Kandel, Germany), diallyldimethylammonium chloride (65 wt% in H2O) and triallylamine (99%) were obtained from Sigma Aldrich. Piperazine, diallylamine (97%) and D2O (99.9%) were purchased from Merck KGaA (Darmstadt, Germany). The polyester filter bags with a maximum mesh size of 90 µm were bought from Rosin Tech Products (Bethpage, NY, USA).
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7

Corrosion Inhibitor Synthesis and Testing

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The API X60 pipe
from which samples used in this work were made from
was obtained from the oil and gas industry in Saudi Arabia. The elemental
composition of the X60 steel is as given in Onyeachu et al.,39 (link) and the sample pretreatment process was as detailed
in the ASTM G1-03.54 The sample surfaces
were abraded to a final 800-grit size using silicon carbide paper.
The chemicals used for the synthesis of the studied inhibitors
were procured from Merck Schuchardt OHG and include diallylamine (99%;
CAS-No: 124-02-7), 1,6-dibromohexane (96%; CAS-No: 629-03-8), 2,2′-azobis(2-methylpropionamidine)dihydrochloride
(AMPD) (97%; CAS-No: 2997-92-4), and tripropyl amine. They were used
as purchased without further purification.
The corrosive medium
was 15 wt % HCl solution prepared by diluting
concentrated hydrochloric acid (37%; purchased from Merck) with distilled
water.
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