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4 protocols using p25 tio2 nanoparticles

1

Synthesis of PVDF-TrFE Nanocomposite

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PVDF–TrFE (70:30) was obtained from Solvay (Paris, France). P25®-TiO2 nanoparticles were provided by EVONIK (Essen, Germany). Sulfuric acid (H2SO4) 99%, sodium hydroxide (NaOH) 97%, N,N-dimethylformamide (DMF) 99%, and methylene (MB) were all purchased from Merck (Darmstadt, Germany).
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2

PVDF–TrFE Nanocomposite Fabrication

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PVDF–TrFE (70:30) was obtained from Solvay (Brussels, Belgium). P25®-TiO2 nanoparticles was kindly supplied by EVONIK (Essen, Germany). MB and N,N-dimethylformamide (DMF) 99% were supplied by Merck. CIP 98% and IBP 98% were obtained from Sigma-Aldrich (Darmstadt, Germany). NaOH 97% was obtained from VWR (Radnor, PA, USA). Milli-Q ultrapure water was used in all experiments.
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3

Synthesis and Characterization of TiO2 Nanoparticle Catalysts

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P25 TiO2 nanoparticles (21 nm,
Evonik), chloroplatinic acid solution (H2PtCl6, 8% v/v, Sigma-Aldrich), trisodium citrate dihydrate (Sigma-Aldrich),
sodium borohydride (NaBH4, 99%, Sigma-Aldrich), melamine
(99%, Sigma-Aldrich), nickel(II) chloride hexahydrate (NiCl2·6H2O, 99.9%, Sigma-Aldrich), sodium hypophosphite
monohydrate (NaH2PO2·H2O, Fischer
Scientific), Nafion solution (5 wt %, Sigma-Aldrich), sodium carbonate
(Na2CO3, 99.9%, Sigma-Aldrich), sodium bicarbonate
(NaHCO3, 99.9%, Sigma-Aldrich), sodium chloride (NaCl,
99.9%, Sigma-Aldrich), acetonitrile (MeCN, Sigma-Aldrich), 13C-sodium bicarbonate (NaH13CO3, 99.9%, Sigma-Aldrich),
PET film (Goodfellow, ES30-FM-000125), CO2 with 2% CH4 (BOC), N2 with 2% CH4 (BOC), and 13CO2 (Sigma-Aldrich).
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4

PLA-TiO2 Nanocomposite Photocatalysis

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The key materials used in this study were polylactic acid, PLA, pellets (3DQF, Leigh, UK), P25 TiO 2 nanoparticles (Evonik Industries, Essen, Germany), methylene blue, MB, (Merk Life Science UK Ltd., Gillingham, UK), phenol (Merk Life Science UK Ltd., Gillingham, UK) and HCl (Fisher Scientific, Hampton, USA). All aqueous solutions were made up using doubly distilled, de-ionised water.
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