A series of Ba
0.
98SiO
3:0.02Eu, Ba
0.
96SiO
3:0.02Eu, and 0.02R (R = Li, K, Na, La, and Y) phosphors were prepared using a conventional solid-state reaction. The BaCO
3 (99+%), SiO
2 (particle size 5~20 nm, 99.5%), Eu
2O
3 (99.99%), K
2CO
3 (99+%), Li
2CO
3 (99+%), Li
2O (97%), Na
2CO
3 (99+%), LaCl
3 (99.99%), and Y
2O
3 (99.99%), purchased from Merck, were used as a raw materials but SiO
2 was used 20% more to obtain a single-phase BaSiO
3 sample. The raw materials were thoroughly mixed in an agate mortar and subsequently fired in air at 1100 °C for 4 h to synthesize the Eu
3+-doped BaSiO
3. The BaSiO
3:Eu
2+ samples were prepared by sintering the BaSiO
3:Eu
3+ samples again under a reduction atmosphere (95% N
2 + 5% H
2) at 1200 °C for 6 h. The specific formulations of the studied samples are shown in
Table 1.
The crystal phase of the obtained samples was identified using an X-ray diffractometer (X’Pert PRO MPD-3040, Malvern Panalytical, Malvern, UK, CuK
α1, λ = 1.5406 Å) operating at 40 kV and 30 mA with a scan speed of 0.02°/sec. The photoluminescence excitation (PLE) and emission (PL) spectra were measured using a fluorescent spectrofluorometer (
JASCO FP-8500, JASCO, Tokyo, Japan) equipped with an integrating sphere (ISF-834, JASCO, Tokyo, Japan). All measurements were performed at room temperature.
Namkhai P, & Jang K. (2022). Co-Doping Effect on the Optical Properties of Eu(2+/3+) Doped in BaSiO3. Materials, 15(19), 6559.