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4 protocols using octane

1

Synthesis of Functionalized Gold Nanoparticles

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Hexadecyl trimethyl ammonium
bromide (CTAB, 99%), gold chloride trihydrate (HAuCl4·3H2O, 99%), 4-mercaptobenzoic acid (4-MBA, 99%), sodium borohydride
(NaBH4, 99%), poly(vinylpyrrolidone) (PVP ≈ 55,000),
and hexadecyl trimethyl ammonium chloride (CTAC, 99%) were purchased
from Sigma-Aldrich. Ascorbic acid (AA, 99.99%), ethanol (99%), and
silver nitrate (AgNO3, 99%) were purchased from Xilong
Scientific. Melamine was obtained from Shanghai Aladdin Biochemical
Technology Co., Ltd. Cyclohexane (99%), dichloromethane (99%), octane
(99%), and methanol were purchased from Sinopharm Group Chemical Reagent
Co., Ltd., Shanghai. The experimental solutions were prepared with
ultra-pure Milli-Q water (18.2 MΩ) or ethanol. The glassware
was soaked in freshly prepared aqua regia and then rinsed with plenty
of ultra-pure Milli-Q water.
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2

Synthesis and Characterization of Glycidyl-Based Polymers

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(±)Glycidol (96%), potassium methylate (95%), 1,1,1-tris(hydroxymethyl)propane (TMP, 98%), 4-(N,N′-dimethyl amino)pyridine (99%), 1,4-dioxane (99%), glycidyl methacrylate (97%), benzophenone (99%), chloroauric acid (48–50%, Au basic), tetraoctylammonium bromide (98%), and sodium borohydride (98%) were purchased from Aladdin Chemical Reagent Corporation (Shanghai, China). Toluene (99.5%), methanol (99.5%), chloroform 99%), diethyl ether (99.7%), dichloromethane (99.5%), dimethyl sulfoxide (99%), Toluene (99.5%), hexane (97%), cyclohexane (97%), decahydronaphthalene (98%), 1-dodecane (98%), and octane (98%) were purchased from Sinopharm Chemical Reagent Corporation (Jiangsu, China). 1-Tetradecane was purchased from Shanghai Xin Ran chemical technology corporation. The samples of HPG, HPG-MA, DSHPG, and Au@DSHPG were prepared in this laboratory according to the procedure shown in Scheme 1.

Preparation of HPG, HPG-MA, DSHPG, and Au@DSHPG

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3

Synthesis of Lead Chalcogenide Nanocrystals

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Lead oxide (PbO, 99.9%) and 1-octadecene (ODE, > 90%), cadmium oxide (99.99%, metals basis), selenium powder (Se, ≥ 99.99%, ≥ 200 mesh), N,N-dimethylformamide (99.8%, anhydrous), butylamine (BTA, ≥ 99%) were bought from Aladdin. Oleic acid (OA, 90%) and Bis(trimethylsilyl) sulfide (TMS, 98%) were bought from Sigma-Aldrich. Lead iodide (99% +) and lead bromide (99%) were purchased from Adamas. Zinc nitrate (Zn(NO3)2, 99%), zinc acetate dehydrate (Zn(Ac)2·2H2O, 99%), ammonium citrate (> 99%), NH4F (> 99%), ethanolamine (> 99%), 2-methoxyethanol (> 99%), octane (≥ 95%), acetone (≥ 99.5%) and methanol (≥ 99.7%) were bought from Sinopharm reagents. All solvents and materials were used directly without further purification.
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4

Chromium-Doped Tin Oxide Synthesis

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All reagents were analytical grade and used without further purification. Chromium nitrate (Cr(NO3)3·9H2O, 99 wt%), stannic chloride (SnCl4·5H2O, 99 wt%), hydrofluoric acid (HF, 49%), anhydrous ethanol (99.5 wt%), pyridine (99.5 wt%), and octane (99.5 wt%) were purchased from Sinopharm Chemical Reagent Co. Ltd., China. Terephthalic acid (H2BDC, 99 wt%) was supplied by Alfa Aesar China Co., Ltd. (Tianjin, China).
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