Log In Sign up
The largest database of trusted experimental protocols

Cu acac 2

Manufactured by Merck Group
Visit Supplier
Sourced in United States

Cu(acac)2 is a copper(II) acetylacetonate complex compound. It is a crystalline solid used as a precursor in chemical synthesis and materials processing.

Automatically generated - may contain errors

Lab products found in correlation

Benzyl alcohol, by Merck Group (2 mentions) Ethanol, by Merck Group (2 mentions) 4 nitrophenol, by Merck Group (1 mentions) Ni acac 2, by Merck Group (1 mentions) Carbon disulfide, by Merck Group (1 mentions) Thf d8, by Merck Group (1 mentions) Sodium hydroxide (naoh), by Carl Roth (1 mentions) Haucl4 3h2o, by Merck Group (1 mentions) Cyanogen bromide, by Merck Group (1 mentions) Copper 2 acetylacetonate, by Merck Group (1 mentions) Primaset badcy, by Lonza (1 mentions) Triphenylphosphine, by Nacalai Tesque (1 mentions) Mgcl2, by Nacalai Tesque (1 mentions) Rh2 oac 4, by Merck Group (1 mentions) 1 hexanol, by Fujifilm (1 mentions) 1 dodecanol, by Nacalai Tesque (1 mentions)

6 protocols using cu acac 2

1

Synthesis of Reduced Graphene Oxide Composites

Check if the same lab product or an alternative is used in the 5 most similar protocols
Reduced graphene oxide (GO, thickness ~ ≤ 3.0 nm, surface area ~ > 600 m2/g and purity ~ > 99 wt %) was supplied by ACS Materials (USA) and used without any further purification. Metal precursors, Ni(acac)2 (97%) and Cu(acac)2, were purchased from Sigma Aldrich (USA). Potassium ferrocyanide (K4Fe(CN)6), sodium borohydride (NaBH4) aryl halides, solvents and 4-nitrophenol were supplied by Sigma Aldrich (USA) or Wako Pure Chemicals (Japan), and used as received.
Mayakrishnan G., Elayappan V., Kim I.S, & Chung I.M. (2020). Sea-Island-Like Morphology of CuNi Bimetallic Nanoparticles Uniformly Anchored on Single Layer Graphene Oxide as a Highly Efficient and Noble-Metal-Free Catalyst for Cyanation of Aryl Halides. Scientific Reports, 10, 677.
+ Open protocol
+ Expand
2

Synthesis of Copper(II) Acetylacetonate

Check if the same lab product or an alternative is used in the 5 most similar protocols
Cu(acac)2 (Copper(II) acetylacetonate, 97%), dimethylamine-borane complex (DMAB, Me2NHBH3, 97%), carbon disulfide (CS2, ≥99%), THF-d8, and hexane (99%) were bought from Sigma-Aldrich. Ethanol was bought from Merck. Acetone was used to clean all glass materials and Teflon-coated magnetic stir bars. All materials were rinsed a few times with copious amounts of distilled water and then dried at high temperature (110°C) in the oven during the night.
ÖZDEMİR A, & DUMAN S. (2021). Green dehydrogenation of dimethylamine borane catalyzed by cheaply copper(0) nanocatalysts without any stabilizer at nearly room temperature. Turkish Journal of Chemistry, 45(6), 1739-1751.
+ Open protocol
+ Expand
3

Synthesis of Gold Nanoparticles

Check if the same lab product or an alternative is used in the 5 most similar protocols
Benzyl alcohol (BnOH) (> 99.8%, anhydrous), Cu(acac)2 (99.99%) and HAuCl4⋅3H2O (≥ 99.9% trace metal basis) were purchased from Sigma-Aldrich, and ethanol (absolute) for washing from VWR. Sodium hydroxide (≥ 99%) was supplied by Carl Roth. All chemicals were used without further purification.
Grote L., Hussak S.A., Albers L., Stachnik K., Mancini F., Seyrich M., Vasylieva O., Brückner D., Lyubomirskiy M., Schroer C.G, & Koziej D. (2023). Multimodal imaging of cubic Cu2O@Au nanocage formation via galvanic replacement using X-ray ptychography and nano diffraction. Scientific Reports, 13, 318.
+ Open protocol
+ Expand
4

Synthesis and Characterization of Dicyanate Ester Monomer

Check if the same lab product or an alternative is used in the 5 most similar protocols
The dicyanate ester monomer 2,2-bis(4-cyanatophenyl)propane (1) (Fig. 1) was supplied by Lonza AG (Visp, Switzerland) (as PRIMASET™ BADCy) and, having confirmed its purity using 1H NMR and elemental analysis, was used as received without further purification. In the interests of brevity, the analytical data (from FTIR ATR, 1H and 13C NMR spectroscopy) are given as ESI.† The synthesis of l,l-dichloro-2,2-(4-cyanatophenyl)ethylidene was based on a well-used route, originally reported by Grigat and Pütter17 (link) Copper(ii) acetylacetonate, Cu(acac)2, (97%) and dodecylphenol (mixture of isomers) (used in the co-catalyst package) and cyanogen bromide (97%) were obtained from Sigma Aldrich. Bisphenol C (l,l-dichloro-2,2-(4-hydroxyphenyl)ethylidene, 97%) was obtained from AOKChem, Shanghai. All reagents were analysed to determine purity and used as received without further purification.
Mooring L., Thompson S., Hall S.A., Pani S., Zioupos P., Swan M., Stone C., Howlin B.J, & Hamerton I. (2018). ‘Phoenix polymers’: fire induced nanohardness in fibril-forming aromatic cyanate esters. RSC Advances, 8(63), 36264-36271.
+ Open protocol
+ Expand
5

Synthesis of Diazoacetates and Reagents

Check if the same lab product or an alternative is used in the 5 most similar protocols
Tetrahydrofuran
(THF) and toluene were dried
over a Na/K alloy and Na, respectively, and distilled before use.
CH2Cl2 was dried over CaH2 and used
without further purification. Cu(acac)2 (TCI; >97%),
Rh2(OAc)4 (AZmax; 99%), RuCl(cod)Cp* (Sigma-Aldrich),
Grubbs first catalyst (Sigma-Aldrich; 97%), 1-hexanol (TCI; >98.0%),
diisopropyl azodicarboxylate (Wako; >90%), triphenylphosphine (Nacalai;
>98.0%), MgCl2 (Nacalai; >97.0%), 1,8-diazabicyclo[5,4,0]-7-undecene
(DBU) (Nacalai; >97.0%), and 1-dodecanol (TCI; >99.0%) were
used as
received without further purification. Tosyl azide,27 4,4′-biphenylenediacetic acid,28 (link) 1,4-phenylenediacetic acid,28 (link),29 (link) and 2,2′-(9,9-dioctyl-9H-fluorene-2,7-diyl)diacetonitrile30 (link) were prepared following the procedures reported in the literatures.
Methyl 2-diazo-2-phenylacetate17 (link) was prepared
using tosyl azide as a diazo transfer agent following a reported general
procedure for this type of diazoketones. Caution! Extra care must
be taken for the preparation and handling of the diazoacetates because
of their potential explosiveness.
Shimomoto H., Moriya T.A., Mori T., Itoh T., Kanehashi S., Ogino K, & Ihara E. (2020). Single-Component Polycondensation of Bis(alkoxycarbonyldiazomethyl)aromatic Compounds To Afford Poly(arylene vinylene)s with an Alkoxycarbonyl Group on Each Vinylene Carbon Atom. ACS Omega, 5(10), 4787-4797.
+ Open protocol
+ Expand
6

Benzyl Alcohol and Cu(acac)2 Synthesis

Check if the same lab product or an alternative is used in the 5 most similar protocols
Benzyl alcohol (>99.8%, anhydrous) and Cu(acac)2 (99.99%) were purchased from Sigma-Aldrich, and ethanol (absolute) for washing from VWR. All chemicals were used without further purification.
Grote L., Seyrich M., Döhrmann R., Harouna-Mayer S.Y., Mancini F., Kaziukenas E., Fernandez-Cuesta I., A. Zito C., Vasylieva O., Wittwer F., Odstrčzil M., Mogos N., Landmann M., Schroer C.G, & Koziej D. (2022). Imaging Cu2O nanocube hollowing in solution by quantitative in situ X-ray ptychography. Nature Communications, 13, 4971.
+ Open protocol
+ Expand

About PubCompare

Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.

We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.

However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.

Ready to get started?

Sign up for free.
Registration takes 20 seconds.
Available from any computer
No download required

Sign up now

Revolutionizing how scientists
search and build protocols!