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5 protocols using aliquat 336

1

Bispyribac Sodium Detection Assay

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Bispyribac sodium (99%), Diquate dibromide (98.3%), Dimethoate (98%) and Cyromazine (98.5%) were purchased from Dr. Ehrenstorfer GmbH (Germany). Methomyl (98.5%) and Oxamyl (99%) were purchased from Fluka (Ronkonkama, NY). Polyaniline (emeraldine salt) (average Mw > 15,000, 3–100 μm particle size), methacrylic acid (MAA), ethylene glycol dimethacrylate (EGDMA), acetonitrile and benzoyl peroxide (BPO) were purchased from Sigma-Aldrich Inc. (St. Louis, MO, USA). Aliquat 336 was purchased from Acros (Spain). High molecular weight poly (vinylchloride) (PVC), dioctyl phthalate (DOP) was obtained from Fluka AG (Buchs, Switzerland). Tetrahydrofuran (THF) was freshly distilled prior to use. For pesticide technical formulation, a Nominee-kz, 3% soluble liquid (SL) of Bispyribac sodium, was purchased from Kafr El-Zayat Pesticides& Chemicals Company (Gharbia, Egypt). All other chemical reagents were of analytical grade and used without any further purification.
A stock Bispyribac sodium solution (10−2 M) was prepared by dissolving 0.45 g pure Bispyribac sodium in 100 mL distilled water. Working solutions (10−2–10−6 M) were prepared by accurate dilutions and stored in brown bottles.
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2

Ruthenium(III) Nitrosyl Nitrate Extraction

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Ruthenium(III) nitrosyl
nitrate solution [Ru(NO)(NO3)x(OH)y, x + y = 3 in dilute nitric acid] has been purchased from Sigma-Aldrich.
Aliquat 336 (91%, Acros organics), isodecyl alcohol (IDA) (98%, Prabhat
Chemical, Mumbai), citric acid monohydrate (Loba Chemie Pvt. Ltd,
Mumbai), and n-dodecane (99%, Alfa Aesar) have been
used without further purification. Electronic grade HNO3 (69–71%, Research-Lab Fine Chem Industries, Mumbai) and NaOH
(98%, Chenkem, Mumbai) are used for maintaining the pH of various
stock solutions used in the experiments. All the dilutions were done
with the help of ultrapure water (LaboStar PRO TWF water purifiers,
Evoqua Water Technology, GmbH). 106Ru tracer was used for
the active experiments.
The organic phase was prepared by mixing
Aliquat 336 and IDA at different proportions (v/v %) in n-dodecane as the diluent. Required amount of citric acid was added
into the aqueous feed solution before performing the solvent extraction
experiments.
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3

Synthesis and Characterization of Polymeric Materials

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Acrylamide
and 3-(dimethylamino)propionitrile
were obtained from Sigma-Aldrich (St. Louis, Missouri, USA). N,N′-Methylenebis(acrylamide) was
obtained from Carl Roth (Karlsruhe, Germany). Potassium persulfate
was obtained from Merck (Darmstadt, Germany). Naphthalene-2-boronic
acid was obtained from Matrix Scientific (Columbia, South Carolina,
US), and Aliquat 336 was obtained from Thermo Fisher Scientific (Kandel,
Germany). Glycoin natural (52.8 w% 2-GG) was obtained from bitop AG
(Dortmund, Germany). Other chemicals were obtained from Carl Roth,
Merck, or Honeywell (Charlotte, North Carolina, USA).
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4

Solvent Extraction Reagent Acquisition

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Aliquat
336 was purchased from Thermo Fisher
Scientific (Merelbeke, Belgium). KBr (≥99%) and di-isobutyl
ketone (DIBK, >96%) were acquired from Acros Organics (Geel, Belgium).
Potassium iodide (KI) (≥99.5%) was bought from Honeywell Riedel
de Haën (Seelze, Germany). KSCN (>99%) and KNO3 (>99%)
were purchased from Chem-Lab (Zedelgem, Belgium). NaHSO4 (>93%) was acquired from Carl Roth (Karlsruhe, Germany). Water
was
always of ultrapure quality (Milli-Q water), deionized with a Merck
Millipore Milli-Q Reference A+ system. All chemicals were used as
received, without any further purification.
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5

Solvent Extraction of Inorganic Salts

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Aliquat 336 was purchased from Thermo Fisher
Scientific (Merelbeke, Belgium). NaBr (≥99.5%) and diisobutyl
ketone (DIBK, >96%) were acquired from Acros Organics (Geel, Belgium).
KI (≥99.5%) was bought from Honeywell Riedel de Haën
(Seelze, Germany). KSCN (>99%) and NaNO3 (>99.5%)
were
purchased from Chem-Lab (Zedelgem, Belgium). Water was of ultrapure
quality and deionized with a Merck Millipore Milli-Q Reference A+
system. All chemicals were used as received without any further purification.
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