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3 protocols using octadecanol

1

Fatty Acids and Hydrocarbons Characterization

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The linear (C7-C30) hydrocarbons, squalene, nonanal, (E)-2-nonenal, (E)-2-decenal, decanal, (E,Z)-2,4-decadienal, nonanol, dodecanol, tetradecanol, hexadecanol, octadecanol, docosanol, nonanoic acid, dodecanoic acid, myristic acid, palmitoleic acid, palmitic acid, linoleic acid, oleic acid, and geranyl acetone were purchased from Sigma-Aldrich, and 2,13-octadecadienol diastereomers were kindly donated by Dr. Wittko Francke from the University of Hamburg.
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2

Synthesis of Functionalized Silica Particles

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Ethanol (99.8%, Merck), Tetraethyl orthosilicate (TEOS, 99%, Sigma-Aldrich), Ammonia solution (NH4OH, 25%, Merck), Polydiallyldimethylammonium chloride (Poly-DADMAC, 400–500 kDa, 20 wt%, Sigma-Aldrich), Trimethoxy[3-(methylamino)propyl]silane (MAPTMS, 97%, Sigma-Aldrich), 1-Octadecanol (Octadecanol, 99%, Sigma-Aldrich), Toluene (99.85%, Fisher Scientific), Toluenesulfonic acid-p monohydrate (pTsOH, 98%, Sigma-Aldrich), Propiolic acid (96%, Sigma-Aldrich), Isopropanol (technical grade), Deionized water (Milli-Q, Merck-Millipore). All products were used as received.
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3

Synthesis of Metal Nanoparticles

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All chemicals, including precursors: iron(III) acetylacetonate (Fe(acac) 3 , 99.99%), cobalt(II) acetylacetonate (Co(acac) 2 , 99%); solvents: dioctyl ether (99%, boiling point: 287 °C), 1-octadecene (90%, boiling point: 320 °C), chloroform (≥99%), absolute ethanol (100%), toluene (99.8%), and hexane (98.5%); surfactants and reductant: oleic acid (OA, 99%), oleylamine (OLA, 70%), 1,2-hexadecanediol (HDD, 90%) and octadecanol (OCD-ol, 99%) were purchased from Sigma-Aldrich Ltd, Singapore. All the chemicals were used as received without further purification.
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