1 3 5 benzenetricarboxylic acid

Manufactured by Merck Group

Sourced in Germany, United States

1,3,5-benzenetricarboxylic acid is a chemical compound with the molecular formula C6H3(COOH)3. It is a crystalline solid that is used as a starting material in the synthesis of various organic compounds.

Automatically generated - may contain errors

Lab products found in correlation

29 protocols using 1 3 5 benzenetricarboxylic acid

Synthesis of Gadolinium-Iron Metal-Organic Frameworks

Check if the same lab product or an alternative is used in the 5 most similar protocols

Example 27

Two Synthetic Conditions are Possible:

Synthesis 1:

0.028 g (0.5 mmol) of metallic iron powder Fe° (Riedel-de Haën, 99%), 0.225 g of gadolinium(III) nitrate hexahydrate (0.5 mmol, Aldrich, 99.9%) and 0.140 g of 1,3,5-benzenetricarboxylic acid (0.666 mmol, Aldrich, 95%) dispersed in 10 ml of deionized water, the whole left for 24 hours at 180° C. in a 23 ml Teflon body placed in a Paar metallic bomb. The solid is then filtered off and washed with water and then with ethanol.

Synthesis 2:

0.065 g (˜0.5 mmol per 1 iron per trimer) of iron(III) acetate (prepared according to the synthesis described in Example 1), 0.225 g of gadolinium(III) nitrate hexahydrate (0.5 mmol, Aldrich, 99.9%) and 0.140 g of 1,3,5-benzenetricarboxylic acid (0.666 mmol, Aldrich, 95%) dispersed in 10 ml of deionized water (or methanol or ethanol or dimethylformamide), the whole left for 12 hours at 150° C. in a 23 ml Teflon body placed in a Paar metallic bomb. The solid is then filtered off and washed with water and then with ethanol.

US10065979B2. Organic/inorganic hybrid nanoparticulates made from iron carboxylates (2018-09-04). None [FR], None [FR], None [FR], None [FR], None [FR]. Inventors: Patricia Horcajada-Cortes [FR], Gérard Ferey [FR], Christian Serre [FR], Ruxandra Gref [FR], Patrick Couvreur [FR].

+ Open protocol

+ Expand

Synthesis of Gadolinium-Iron Metal-Organic Frameworks

Check if the same lab product or an alternative is used in the 5 most similar protocols

Example 27

Two synthetic conditions are possible:

Synthesis 1:

0.028 g (0.5 mmol) of metallic iron powder Fe⁰(Riedel-de Haën, 99%), 0.225 g of gadolinium(III) nitrate hexahydrate (0.5 mmol, Aldrich, 99.9%) and 0.140 g of 1,3,5-benzenetricarboxylic acid (0.666 mmol, Aldrich, 95%) dispersed in 10 ml of deionized water, the whole left for 24 hours at 180° C. in a 23 ml Teflon body placed in a Paar metallic bomb. The solid is then filtered off and washed with water and then with ethanol.

Synthesis 2:

0.065 g (˜0.5 mmol per 1 iron per trimer) of iron(III) acetate (prepared according to the synthesis described in Example 1), 0.225 μg of gadolinium(III) nitrate hexahydrate (0.5 mmol, Aldrich, 99.9%) and 0.140 g of 1,3,5-benzenetricarboxylic acid (0.666 mmol, Aldrich, 95%) dispersed in 10 ml of deionized water (or methanol or ethanol or dimethylformamide), the whole left for 12 hours at 150° C. in a 23 ml Teflon body placed in a Paar metallic bomb. The solid is then filtered off and washed with water and then with ethanol.

US10738068B2. Organic/inorganic hybrid nanoparticulates made from iron carboxylates (2020-08-11). CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE—CNRS [FR], UNIVERSITÉ DE VERSAILLES—SAINT-QUENTIN-EN-YVELINES [FR]. Inventors: Patricia Horcajada-Cortes [FR], Gérard Ferey [FR], Christian Serre [FR], Ruxandra Gref [FR], Patrick Couvreur [FR].

+ Open protocol

+ Expand

VEGF-Based Protein Conjugation Protocol

Check if the same lab product or an alternative is used in the 5 most similar protocols

Human recombinant VEGF₁₆₅, anti-VEGF₁₆₅ antibody, N-hydroxysuccinimide (NHS), 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride (EDC), dimethylformamide (DMF) and ethanol (95%) were purchased from Sigma-Aldrich, India. Just to highlight that anti-VEGF antibody and VEGF₁₆₅ were stored at 4 °C and −20 °C, respectively, before use. Freshly aqueous solutions of EDC and NHS were prepared before using. All solutions were prepared using deionized water (DI) from a Millipore system. Cobaltous chloride, potassium ferricyanide, 1,3,5-benzenetricarboxylic acid (BTC) and GO were purchased from Merck. Sodium dihydrogen orthophosphate dehydrate (Merck) and sodium phosphate dibasic dehydrate (Sigma-Aldrich) were used to prepare a 0.1 M phosphate buffer of different pH to carry out pH study. All chemicals were of analytical grade and used without any further purification.

Singh S., Numan A., Zhan Y., Singh V., Alam A., Van Hung T, & Nam N.D. (2020). Low-potential immunosensor-based detection of the vascular growth factor 165 (VEGF165) using the nanocomposite platform of cobalt metal–organic framework. RSC Advances, 10(46), 27288-27296.

+ Open protocol

+ Expand

Synthesis of Metal Complexes

Check if the same lab product or an alternative is used in the 5 most similar protocols

All used materials including, acetonitrile, Lithium perchlorate, 4-Amino Benzoic acid, Sodium nitrite, Methanol, 1,3,5-benzene tricarboxylic acid, and alcohols were purchased from Merck. Hydrochloric acid, Potassium tetrafluoroborate, Co(NO₃)₂. 6H₂O, Dimethylformamide were purchased from Sigma-Aldrich. All chemicals have been used without further purification.

Khakyzadeh V, & Sediqi S. (2022). The electro-oxidation of primary alcohols via a coral-shaped cobalt metal–organic framework modified graphite electrode in neutral media. Scientific Reports, 12, 8560.

+ Open protocol

+ Expand

BTC Synthesis and Characterization

Check if the same lab product or an alternative is used in the 5 most similar protocols

The chemical reagents used were of analytical grade, and solutions were prepared with twice-distilled water (from here on out, “water”).
To begin, 1,3,5-Benzenetricarboxylic acid (≥95%) (BTC) was supplied by Merck (Darmstadt, Germany). Hydrochloric acid 37% (HCl), hydroquinone and sodium hydroxide (NaOH) were obtained from PanReac Química (Castellar del Vallès, Barcelona, Spain). Acetonitrile, acrolein (≥95.0%, ~0.2% hydroquinone as stabilizer), deuterium oxide (D₂O), and 3-(trimethylsilyl)-2,2,3,3-tetradeuteropropionic acid sodium salt (TSP) were purchased from Sigma-Aldrich (St. Louis, MO, USA).

de las Heras E., Zuriarrain-Ocio A., Zuriarrain J., Bordagaray A., Dueñas M.T, & Berregi I. (2020). Quantitative Determination of Acrolein in Cider by 1H NMR Spectrometry. Foods, 9(12), 1820.

+ Open protocol

+ Expand

Peanut Shell-derived Adsorbent for Water Purification

Check if the same lab product or an alternative is used in the 5 most similar protocols

Peanut shells were purchased from a grocery store and used as the raw materials. Sodium hypochlorite solution (6–14%), copper nitrate trihydrate (Cu(NO₃)₂·3H₂O), sulfuric acid (95–98 wt%), 1,3,5-benzene tricarboxylic acid (BTC), N,N'-methylene bisacrylamide (MBA), and other reagents (NaOH, HNO₃, CHCl₃, EtOH, t-butyl alcohol and Congo Red) were all purchased from Merck. Deionized water (resistivity 18.2 MΩ/cm) was used in all cases. All the chemicals in this study were used as received without any further purification.
FTIR measurements were conducted on Nicolet 6700 Fourier transform infrared spectrometer. Scanning electron microscopy (SEM) measurements were conducted on Hitachi S-4800 instruments operated at 2 kV for gold-sputtered samples. XRD patterns were recorded on a Bruker D8 ADVANCE X-ray diffractometer with a Cu Ka radiation (λ = 1.5418 Å). The powder was leveled on sample holders and scanned with a 2θ angle from 5° to 50° with a step speed of 5°/min. The concentration of the contaminated water was determined using a DU 800 UV–Vis spectrophotometer. The amounts of Mn²⁺ and Mn⁷⁺ were determined by Inductively Coupled Plasma (ICP) analysis on sequential plasma spectrometer, Shimadzu (ICPS-7000).

Shaheed N., Javanshir S., Esmkhani M., Dekamin M.G, & Naimi-Jamal M.R. (2021). Synthesis of nanocellulose aerogels and Cu-BTC/nanocellulose aerogel composites for adsorption of organic dyes and heavy metal ions. Scientific Reports, 11, 18553.

+ Open protocol

+ Expand

Synthesis of NENU-5 Nanocrystals

Check if the same lab product or an alternative is used in the 5 most similar protocols

All chemicals were purchased and used without further purification. In a typical synthesis, 1 mmol of copper (II) acetate monohydrate (Sigma-Aldrich), 0.5 mmol of L-glutamic acid (Sigma-Aldrich) and 0.3 g of phosphomolybdic acid hydrate (Sigma-Aldrich) were dissolved in 40 ml of deionized water and stirred at ambient condition for 20 min. After that, 0.67 mmol of 1,3,5-benzenetricarboxylic acid (Merck) completely dissolved in 40 ml of ethanol was poured into the above solution under continuous stirring. The solution immediately turns turbid due to the rapid formation of NENU-5 nanocrystals. After stirring for 14 h at ambient condition, the green precipitate was collected by centrifugation and washed twice with ethanol. The product was dried at 70 °C overnight for further experiment and characterizations. The size of the NENU-5 particles can be easily tuned by varying the added amount of L-glutamic acid.

Wu H.B., Xia B.Y., Yu L., Yu X.Y, & Lou X.W. (2015). Porous molybdenum carbide nano-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production. Nature Communications, 6, 6512.

+ Open protocol

+ Expand

Functionalization of Wood Samples

Check if the same lab product or an alternative is used in the 5 most similar protocols

European beech (Fagus sylvatica), American basswood (Tilia americana), and Norway spruce (Picea abies) wood samples were cut into cuboids with the dimensions 10 × 10 × 5 mm³ (radial × tangential × longitudinal, R × T × L). Tangential cut beech samples with a thickness of 6 mm, a length of 6 cm, and a width of 2 cm were used. Zinc nitrate hexahydrate (Zn(NO₃)₂·6H₂0, 98%), copper(II) acetate (Cu(OAc)₂, 98%), triethylamine (C₃H₉N, ≥99%), and sodium chloroacetate (ClCH₂COONa, 98%) were purchased from Sigma‐Aldrich. 2‐Methylimidazole (2‐MeIm, C₆H₆N₂, 97%) and sodium hydroxide (NaOH) were supplied by Thermo Fisher GmbH. 1,3,5‐benzenetricarboxylic acid was obtained from EMD Millipore Corporation. M ethanol (≥99.9%), ethanol (≥99.8%), and N,N‐dimethyformamide (DMF, ≥99.8%, Sigma‐Aldrich) were used as solvents. All chemicals were used as received.

Tu K., Puértolas B., Adobes‐Vidal M., Wang Y., Sun J., Traber J., Burgert I., Pérez‐Ramírez J, & Keplinger T. (2020). Green Synthesis of Hierarchical Metal–Organic Framework/Wood Functional Composites with Superior Mechanical Properties. Advanced Science, 7(7), 1902897.

+ Open protocol

+ Expand

Lanthanide-based Metal-Organic Framework Synthesis

Check if the same lab product or an alternative is used in the 5 most similar protocols

Yttrium(III) acetate hydrate and Europium(III) acetate hydrate were purchased from STREM Chemicals, and the 1,3,5-benzenetricarboxylic acid was purchased from Sigma-Aldrich. All the reagents were used without other purifications. Two different sets of syntheses have been performed. Scheme 1 provides a summary of the process.

Lo Presti F., Pellegrino A.L., Consoli N, & Malandrino G. (2023). Green Ultrasound-Assisted Synthesis of Rare-Earth-Based MOFs. Molecules, 28(16), 6088.

+ Open protocol

+ Expand

Synthesis of Metal-Organic Frameworks

Check if the same lab product or an alternative is used in the 5 most similar protocols

All chemicals and reagents were utilized, without additional purification. Ni(NO₃)₂·6H₂O; 1,3,5-benzenetricarboxylic acid (BTC), terephthalic acid (TPA), 2-aminoterephthalic acid (ATPA), 2,5-dihydroxyterephthalic acid (DHTPA), dimethylformamide (DMF), ethanol, KOH, methanol, acetone, absolute ethanol (99.9%), acetic acid, ethylene glycol, 1-ethyl-3-methylimidazolium tetrafluoroborate, fluorine doped tin oxide (FTO) coated soda-lime glass substrate (SLG), were pursed from Sigma Aldrich, Germany.

Ariful Islam M., Selvanathan V., Chelvanathan P., Mottakin M., Aminuzzaman M., Adib Ibrahim M., Muhammad G, & Akhtaruzzaman M. (2023). Metal organic framework derived NiOx nanoparticles for application as a hole transport layer in perovskite solar cells. RSC Advances, 13(19), 12781-12791.

+ Open protocol

+ Expand

About PubCompare

Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.

We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.

However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.

Ready to get started?

Revolutionizing how scientists
search and build protocols!