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2 protocols using aqueous solutions of hydrogen peroxide

1

Synthesis of Gold-Metal Complexes

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Chemicals were purchased from commercial sources and used without further purification. Aqueous solutions of hydrogen peroxide (30 wt%) were purchased from Wako Pure Chemical Industries. Ultra-pure water was obtained from a Millipore Direct-Q3 UV water purification system, wherein the electronic conductance was 18.2 MΩ cm–1. [AuI4CoIII2(dppe)2(d-pen)4]Xn ([1]Xn, Xn = (Cl)2, (ClO4)2, (NO3)2 or SO42–), [Au4Cr2(dppe)2(d-pen)4]Cl2, [CoIII{AuI(PPh3)(d-pen)}2]ClO4 ([2]ClO4) and [Au2(dppe)(d-Hpen)2] were prepared according to the methods reported in the literature.11a ,18
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2

Synthesis and Characterization of Metal Complexes

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Chemicals were purchased from commercial sources and used without further purification, unless otherwise noted. Tetraethyl orthosilicate, cetyltrimethylammonium bromide, sodium aluminate, sodium hydroxide, aqueous solutions of hydrogen peroxide (30 wt%) and perchloric acid (60%) were purchased from Wako Pure Chemical Industries. Tris(2-pyridylmethyl)amine and oxo[5,10,15,20-tetra(4-pyridyl)porphyrinato]titanium(iv) (Ti–TPyP) were supplied from Tokyo Chemical Industry. Copper(ii) perchlorate hexahydrate was supplied by Sigma-Aldrich. Acetone and acetonitrile were purchased from Nacalai tesque as a spectral grade and used as received. Ultra-pure water was provided by a water purification system, Millipore Direct-Q3 UV, wherein the electronic conductance was 18.2 MΩ cm. Benzene was purchased from Wako Pure Chemical Industries and purified by washing with sulphuric acid and water following distillation. [Cu(tmpa)(CH3CN)](ClO4)2, [Cu(tepa)(ClO4)]ClO4, [CuII2(N5)(H2O)2](NO3)4 and Al-MCM-41 were synthesised by literature methods.53a ,61 (link)–64
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