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2 furanmethanethiol

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2-furanmethanethiol is a chemical compound used in laboratory settings. It is a clear liquid with a characteristic odor. The core function of this product is as a chemical reagent or intermediate for various scientific and analytical applications.

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Lab products found in correlation

Furfural d4, by CDN Isotopes (1 mentions) 2 acetylfuran, by Merck Group (1 mentions) Ethyl 2 furoate, by Merck Group (1 mentions) Homofuraneol, by Merck Group (1 mentions) 3 acetyl 2 5 dimethylfuran, by Merck Group (1 mentions) 2 3 dihydrobenzofuran, by Merck Group (1 mentions) Milli q water, by Merck Group (1 mentions) Caffeic acid, by Merck Group (1 mentions) Caftaric acid, by Merck Group (1 mentions) Furfural, by Merck Group (1 mentions) 5 methylfurfural, by Merck Group (1 mentions) N hydroxysuccinimide, by Merck Group (1 mentions) 6 maleimidohexanoic acid, by Merck Group (1 mentions) Tris 2 carboxyethyl phosphine hydrochloride solution tcep, by Merck Group (1 mentions) Antifoam a, by Merck Group (1 mentions) 1 ethyl 3 3 dimethylaminopropyl carbodiimide hydrochloride edc, by Thermo Fisher Scientific (1 mentions) Methanol, by Merck Group (1 mentions) Formaldehyde, by Merck Group (1 mentions) Sodium hydroxide (naoh), by Merck Group (1 mentions) Isopropanol, by Merck Group (1 mentions)

4 protocols using 2 furanmethanethiol

1

Quantification of Furan Derivatives in Food

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The deuterated internal standards of caffeic acid-d6 (CAS 2708298-33-1, ≥99%) and furfural-d4 (CAS 1219803-80-1, ≥98%) were purchased from CDN Isotopes (Pointe-Claire, QC, Canada). furfural ethyl ether (CAS 6270-56-0, ≥97%) was purchased from Fisher Scientific (Hampton, NH, USA). The following compounds were purchased from Sigma-Aldrich Inc. (Oakville, ON, Canada); caffeic acid (CAS 331-39-5, ≥98%), caftaric acid (CAS 67879-58-7, ≥97%), 3-acetyl-2,5-dimethylfuran (CAS 10599-70-9, ≥98%), 2-furanmethanethiol (CAS 98-02-2, ≥98%), 2,3-dihydrobenzofuran (CAS 496-16-2, ≥99%), 2-acetylfuran (CAS 1192-62-7, ≥99%), 5-methylfurfural (CAS 620-02-0, ≥98%), homofuraneol (CAS 27538-09-06, ≥96%), furfural (CAS 98-01-1, ≥99%), sodium chloride (NaCl, ≥99%) and ethyl-2-furoate (CAS 614-99-3, ≥99%). All solvents used were HPLC grade purity. Potassium metabisulphite (KMS) and potassium bitartrate (cream of tartar) were purchased from Scott Laboratories Ltd. (Niagara-on-the-Lake, ON, Canada). D-fructose (≥99%) was purchased from BioShop® Canada Inc. (Burlington, ON, Canada). Milli-Q water was obtained Millipore (Saint-Quentin-en-Yvelines, France).
Medeiros J., Xu S., Pickering G.J, & Kemp B.S. (2022). Influence of Caffeic and Caftaric Acid, Fructose, and Storage Temperature on Furan Derivatives in Base Wine. Molecules, 27(22), 7891.
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2

Synthesis of FAM-tagged miR148b Oligonucleotides

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Custom-modified fluorescein amidites (FAM)-tagged oligonucleotides (miR148b: 5’ 6-FAM 2’OMe UCA GUG CAU CAC AGA ACU UUG U C6-NH2 3’) were acquired through Trilink Biotechnologies, LLC. (San Diego, CA). 6-Maleimidohexanoic acid (90%), 2-furanmethanethiol (98%), methanol (>99.9%), isopropanol (>99.9%), dichloromethane (99.8%), N-hydroxysuccinimide (NHS) (98%), silver nitrate (99%), formaldehyde (36.5%-38%), sodium hydroxide (98%, pellets), hydroxypropyl cellulose (HPC, Mn = 80,000, 99%), antifoam A (100%), tris(2-carboxyethyl)phosphine hydrochloride solution (TCEP) (0.5M), were all purchased and used without alteration from Sigma Aldrich (St. Louis, MO). EDC (1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride), was purchased from ThermoFisher Scientific (Waltham, MA). Mounted 415nm LED lights from ThorLabs, Inc. (Newton, NJ) were used for photo-release experiments.
Liu Y., Bailey J.T., Abu-Laban M., Li S., Chen C., Glick A.B, & Hayes D.J. (2020). Photocontrolled miR-148b nanoparticles cause apoptosis, inflammation and regression of Ras induced epidermal squamous cell carcinomas in mice. Biomaterials, 256, 120212.
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3

Quantification of Aroma Compounds by GC-MS

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The following reference compounds: acetic acid, acetoin, 2-methylbutanal, 2-methylpyrazine, 2,5-dimethylpyrazine, 2-furanmethanethiol, 2-acetyl-1-pyrroline, benzaldehyde, 1-octen-3-one, octanal, linalool, 2-acetylthiazole, 2-acetylpyridine, 4-hydroxy-2,5-dimethyl-3(2H)-furanone, 2-methoxyphenol, 3-hydroxy-4,5-dimethyl-2(5H)-furanone, hexadecanol, octadecanal, 2.3-pentanedione, butanoic acid, β-iso-methyl ionone, β-ionone, were from Sigma-Aldrich (St. Louis MO). Stock standard solutions 103 or 104 µg mL−1 of each compound was prepared as described earlier [21 (link)].
Lasekan O., Muniady M., Lin M, & Dabaj F. (2018). Identification of characteristic aroma compounds in raw and thermally processed African giant snail (Achatina fulica). Chemistry Central Journal, 12, 43.
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4

Analytical Characterization of Volatile Thiols

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Mass spectrometry grade dichloromethane and methanol (MS SupraSolv®) were purchased by Merck (Darmstadt, Germany). Water was of ultrapure milli-Q grade. Ammonium formate was from Sigma. Nitrogen (Alphagaz, purity 99.999%, Air Liquid) was used in the Orbitrap-Exactive as the nebulization and fragmentation gas.
Ebselen (2-phenyl-1,2-benzisoselenazol-3(2H)-one, purity 98%), ethylenediaminetetraacetic acid (EDTA) (purity 98,5%);4-methoxy-α-toluenethiol (IS, purity 90%); 4-mercapto-1-butanol (4MB) (purity 95%); 3-mercapto-3-methylbutan-1-ol (3MMB) (purity 98%); 2-methyl-3tetrahydrofuranthiol (2MTHFT) (purity 97%); 3-mercaptohexanol (3MH) (purity 98%); ethanethiol (ET) (purity 97%); 3-mercapto-3-methylbutylformate (3MMBF) (purity 97.5%) and 2-furanmethanethiol (2FMT) (purity 97%) were purchased by Sigma-Aldrich (St Louis, MO, USA). Molecular structures of the reference thiols are shown in Fig. 1.
Quintanilla-Casas B., Dulsat-Serra N., Cortés-Francisco N., Caixach J, & Vichi S. (2015). Thiols in brewed coffee: Assessment by fast derivatization and liquid chromatography–high resolution mass spectrometry. Lebensmittel-Wissenschaft + [i.e. und] Technologie. Food science + technology. Science + technologie alimentaire, 64(2).
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