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5 protocols using acetate hydrate

1

Synthesis of Rare-Earth Nanocrystals

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Gadolinium(iii) acetate hydrate (Gd(CH3CO2)3·xH2O, 99.9%), ytterbium(iii) acetate hydrate (Yb(CH3CO2)3·4H2O, 99.95%), thulium(iii) acetate hydrate (Tm(CH3CO2)3·xH2O, 99.9%), europium(iii) acetate hydrate (Eu(CH3CO2)3·xH2O, 99.9%), sodium hydroxide pellets (NaOH, 98%), ammonium fluoride (NH4F, 99.99%), 1-octadecene (1-ODE, 90%), oleic acid (OA, 90%), methanol (99.8%), anhydrous ethanol (EtOH), acetone (99.9%), cyclohexane (99.5%), hydrochloric acid (HCl, 37%) and nitric acid (HNO3, 70%), sodium chloride (NaCl, 99%), copper(ii) sulfate (CuSO4, 99.99%), cobalt(ii) sulphate heptahydrate (CoSO4·7H2O, 99%), nickel(ii) sulphate hexahydrate (NiSO4·6H2O, 98%), calcium(ii) chloride (CaCl2, 96%), barium(ii) chloride (BaCl2, 99.9%), zinc(ii) nitrate hexahydrate (Zn(NO3)2·6H2O, 98%), lead(ii) nitrate (Pb(NO3)2, 99%), iron(iii) nitrate nonahydrate (Fe(NO3)3·9H2O, 98%), chromium(iii) nitrate nonahydrate (Cr(NO3)3·9H2O, 99.99%), and manganese(ii) acetate tetrahydrate (Mn(CH3CO2)2·4H2O, 99%) were purchased from Sigma-Aldrich. CFCs were purchased from CeTech (W0S1002). All materials were used without further purification unless mentioned specifically.
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2

Synthesis of Luminescent Lanthanide Nanoparticles

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Yttrium(iii) acetate hydrate (99.9%, ALFA Aesar), ytterbium(iii) acetate hydrate (99.9%, ALFA Aesar), thulium(iii) acetate hydrate (99.9%, ALFA Aesar), oleic acid (90%, Sigma-Aldrich), 1-octadecene (90%, ACROS), ammonium fluoride (98%, Merck), sodium hydroxide (98%, Merck), cyclohexane (99%, JT Baker), tetraethyl orthosilicate (99.0%, Sigma-Aldrich), methanol (99.9%, Fisher), hexadecyltrimethylammonium chloride (≥98.0%, Sigma-Aldrich), hydrochloric acid (37%, Sigma-Aldrich), polyethylenimine (branched, Mw 70 000, 30% w/v aq., Polysciences), phosphate buffered saline (powder, pH 7.4, Sigma-Aldrich), trypsin–EDTA (0.5%, no phenol red, Thermo Fisher Scientific), and ethanol (99.5%, Sigma-Aldrich) were used in the experiments. All chemicals were of analytical grade and were used as received without further purification.
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3

Synthesis of Terbium and Europium Complexes

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Terbium(iii) acetate hydrate (99.9% trace metals basis), europium(iii) acetate hydrate (99.9% trace metals basis) benzene-1,3,5-tricarboxylic acid (95%) were purchased from Sigma-Aldrich chemical company and used as received. Dry solvent (i.e. N,N-dimethyl formamide (DMF)) was used for entire work.
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4

Synthesis of Rare-Earth Oxide and Acetate Nanoparticles

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yttrium(III) oxide (Y2O3, 99.99%), ytterbium (III) oxide (Yb2O3, 99.9%), erbium (III) oxide (Er2O3, 99.99%), neodymium (III) oxide (Nd2O3, 99.99%), yttrium (III) acetate hydrate (Y(CH3COO)3, 99.99%), ytterbium (III) acetate tetrahydrate (Yb(CH3COO)3•4H2O, 99.99%), neodymium (III) acetate hydrate (Nd(CH3COO)3, 99.99%), trifluoroacetic acid (CF3COOH, 99%), sodium trifluoroacetate (CF3COONa, 98%), oleic acid (90%, tech grade) and octadecene (90%, tech grade), Indocyanine green, ammonia fluoride (NH4F, ≥99.99% trace metals basis), sodium hydroxide (NaOH, anhydrous, ≥97%) were obtained from Sigma Aldrich. Methanol (ACS reagent grade, ≥99.8%) and hexane (ACS reagent grade, ≥98.5%) were purchased from Fisher Scientific. All chemical reagents were used as received without any further purification.
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5

Synthesis of Lanthanide-Doped Nanoparticles

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Gadolinium (III) acetate hydrate (99.9%) (Gd(OAc)3), ytterbium (III) acetate hydrate (99.9%) (Yb(OAc)3), erbium (III) acetate hydrate (99.9%) (Er(OAc)3), oleic acid (90%) (OA), 1-octadecene (90%) (1-ODE), sodium hydroxide (≥98%) (NaOH), ammonium fluoride (99.9%) (NH4F), methanol (99.9%) (MeOH), cyclohexane (99.5%) (CH), nitrosyl tetrafluoroborate (95%) (NOBF4), chloroform (99%) (CHCl3), dimethylformamide (99.8%) (DMF), copper (II) nitrate (99.999%) (Cu(NO3)2), hydrazine (35 wt % in H2O) (N2H4), 2-propanol (C3H8O), and ammonia borane (90%) (AB) were all purchased from Sigma Aldrich (St. Louis, MO, USA) and used without further purification. Ethanol (EtOH) was purchased from VWR and used as is. Ultrapure water (18.2 MΩ·cm resistivity, PURELAB Ultra Ionic Polishing system) was used for all experiments.
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