Diallymethylamine

PPO (Mn 20,000 and Polydispersity ~2.5) was purchased from Polysciences, Inc. Chlorobenzene (ACS reagent, ≥99.5%), N-methyl-2-pyrrolidone (NMP, reagent grade), tetrahydrofuran (THF, ACS, >99%), diethyl ether (>99%), 1,2-dichloroethane (99.8%), allyl bromide (98%), allyl chloride (98%) and chloroform (99.8%) were purchased from Alfa Aesar (Thermo Fisher, Kandel, Germany). Diallymethylamine (97%) and piperidine (≥99%) were bought from ABCR GmbH (Karlsruhe, Germany). Dimethyl sulfoxide-d₆ (DMSO-d₆, 99.9%) was supplied from Acros Organics ((Thermo Fisher, Kandel, Germany). N-bromosuccinimide (NBS, 99%), 2,2′-azobis(2-methylpropionitrile) (AIBN, 98%), methanol (99.9%) and chloroform-d (CDCl₃-d, 99.9% D) were purchased from Sigma-Aldrich (Merck KGaA, Darmstadt, Germany). 2-hydroxy-4′-(2-hydroxyethoxy)-2-methylpropiophenone (Irgacure D-2959) was bought from Ciba Specialty Chemicals Inc (Basel, Switzerland). Cellophane™ 350PØØ was purchased from Futamura Chemical Co. Ltd. (Hamburg, Germany). Celgard^® membranes were kindly provided by Celgard, LLC (France). Zirfon^® and PBI^® were provided by AGFA Gevaert NV (Mortsel, Belgium) and Fumatech BWT GmbH (Bietigheim-Bissingen, Germany), respectively. All chemicals were used without further purification.

All chemicals, if not specified otherwise, were used as received without further purification. Poly (2,6-dimethyl-1,4-phenyleneoxide) (PPO) (M_n = 20,000, Đ = 2.5) was purchased from Polysciences Inc. and dried under vacuum at 60 °C overnight before use. Methanol (99.9%), ethanol (99.9%) and chloroform (99.8%) were purchased from Fisher Scientific. N-Bromosuccinimide (NBS) (99%), 2,2′-azobis(2-methylpropionitrile) (AIBN) (98%), tetrahydrofuran (THF, ACS, >99%), diethyl ether (>99%), chloroform-d (CDCl₃-d, 99.9% D), Irgacure^® 2959, D₂O (99.9% D) and 1,2-dichloroethane (99.8%) were purchased from Sigma-Aldrich (Merck KGaA, Darmstadt, Germany). Dimethyl sulfoxide-d₆ (DMSO-d₆, 99.9%), N-methyl-2-pyrrolidone (NMP, reagent grade) were supplied from Acros Organics. Chlorobenzene (ACS reagent, ≥99.5%), diallymethylamine (97%) and piperidine (≥99%) were bought from ABCR GmbH. Allyl bromide (98%) and allyl chloride (98%) were bought from Alfa Aesar. The electrolytes MV and TMA-TEMPO were provided by JenaBatteries GmbH (Jena, Germany). FAA-3-50^® was purchased from Fumatech BWT GmbH (Bietigheim-Bissingen, Germany).