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3 protocols using hcooh

1

Selenocompound Analysis in Biological Samples

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Deionized water (Millipore system) was used in this study for chemical preparation. All chemicals used (e.g., Tris, HCl, H2O2, HCOOH, NaOH and (NH4)2HPO4) were analytical grade or above, provided by Sinopharm Chemical Reagent (Shanghai, China). A 1000 mg/L Se stock standard solution was purchased from Merck Millipore (Darmstadt, Germany). Besides, Protease K (30 U/mg), Protease XIV (5.5 U/mg), selenomethionine (SeMet, >98%), selenocystine (SeCys2, >98%), and Se-methylselenocysteine (SeMeSeCys, >98%) were obtained from Sigma-Aldrich (St. Louis, MO, USA).
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2

Synthesis of Pt-Pd Electrocatalysts

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H2PtCl6·6H2O, PdCl2, KOH, HCOOH and H2SO4 were purchased from Sinopharm Chemical Reagent Co., Ltd. All chemicals were of analytical grade purity. Carbon black was obtained from Suzhou Baohua Carbon Black Co., Ltd. A deionized water (resistance: 18.25 MΩ cm−1) was used for the preparation of aqueous solution.
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3

Deuterium-Labeled Acid Catalysts Synthesis

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Ti3AlC2 powder, HCOOH (98%), and HF (≥40%) were obtained from Sinopharm Chemical Reagent Co., Ltd. Pt/C (5% mass loading) and Pd/C (5% mass loading) were obtained from Sigma-Aldrich. DCOOH (95 wt.% in H2O, 98 atom% D), HCOOD (95 wt.% in D2O, 98 atom% D), and DCOOD (95 wt.% in D2O, 98 atom% D) were purchased from Sigma-Aldrich Co. All solvents and chemicals were of analytical grade and used as received without further purification. All aqueous solutions were prepared using deionized water with a resistivity of 18.2 MΩ cm−1.
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