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1 4 benzenedicarboxylic acid h2bdc

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1,4-benzenedicarboxylic acid (H2BDC) is a chemical compound with the molecular formula C6H4(COOH)2. It is a white, crystalline solid used as a precursor in the synthesis of various organic compounds.

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Lab products found in correlation

N n dimethylformamide (dmf), by Merck Group (4 mentions) Hydrochloric acid (hcl), by Merck Group (3 mentions) Dichloromethane, by Merck Group (1 mentions) Chitosan, by Polysciences (1 mentions) Zinc nitrate hexahydrate, by Merck Group (1 mentions) Acetic acid, by Polysciences (1 mentions) Ethanol, by Merck Group (1 mentions) Methanol, by Merck Group (1 mentions) Sodium hydroxide (naoh), by Merck Group (1 mentions) Chloroform, by Merck Group (1 mentions) Acetone, by Merck Group (1 mentions) Gadolinium nitrate hexahydrate, by Merck Group (1 mentions) Zrcl4, by Merck Group (1 mentions) Zrocl2 8h2o, by Merck Group (1 mentions) Sodium acetate, by Merck Group (1 mentions) Sodium phosphate dibasic heptahydrate, by Merck Group (1 mentions) Milli q system, by Merck Group (1 mentions) Dimethyl sulfoxide (dmso), by Merck Group (1 mentions) 3 3 5 5 tetramethylbenzidine (tmb), by Merck Group (1 mentions) Tris edta, by Merck Group (1 mentions)

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H2BDC (4 citations)

6 protocols using 1 4 benzenedicarboxylic acid h2bdc

1

Synthesis of Metal-Organic Framework

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Zinc
nitrate hexahydrate
(99%), 1,4-benzenedicarboxylic acid (H2BDC) (98%), N,N′-dimethylformamide (DMF) (99.8%),
and dichloromethane (DCM) (99.8%) were purchased from Sigma Aldrich
and used without further purification. Chitosan (MW = 50,000–190,000 Da) (≥ 75%) and acetic
acid were purchased from Polysciences. Glycerol, as an IL (99.5%),
was purchased from Quarek Corp company. All chemicals were used without
further purification.
Ali A., Alzamly A., Greish Y.E., Bakiro M., Nguyen H.L, & Mahmoud S.T. (2021). A Highly Sensitive and Flexible Metal–Organic Framework Polymer-Based H2S Gas Sensor. ACS Omega, 6(27), 17690-17697.
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2

Gadolinium-Based Metal-Organic Framework Synthesis

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Gadolinium nitrate hexahydrate
[Gd(NO3)3·6H2O], 1,4-benzenedicarboxylic
acid (H2BDC), and Qt (95%) were purchased from Sigma-Aldrich.
DMF, ethanol, methanol, acetone, chloroform, hydrochloric acid (HCl,
0.1 M), and sodium hydroxide (NaOH, 0.1 M) were supplied by Merck.
All chemicals were of reagent grade and used without further purification.
Tajahmadi S., Shamloo A., Shojaei A, & Sharifzadeh M. (2022). Adsorption Behavior of a Gd-Based Metal–Organic Framework toward the Quercetin Drug: Effect of the Activation Condition. ACS Omega, 7(45), 41177-41188.
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3

Synthesis of Zirconium-based MOF

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ZrCl4, 1,4-Benzenedicarboxylic acid (H2bdc), ethanol, acetone and N,N-Dimethylformamide (DMF) were purchased from Sigma-Aldrich. ZrOCl2•8H2O was purchased from Merck Millipore.
All reagents were used as received, except for DMF, which was treated as detailed in the following to remove traces of water.
Taddei M., van Bokhoven J.A, & Ranocchiari M. (2020). Influence of Water in the Synthesis of the Zirconium-Based Metal-Organic Framework UiO-66: Isolation and Reactivity of [ZrCl(OH)2(DMF)2]Cl. Inorganic chemistry, 59(11).
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4

Zirconium Oxynitrate Hydrate Nanocomposite Synthesis

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Zirconium (IV) oxynitrate hydrate (Zr), praseodymium (Pr), 1,4-benzene-dicarboxylic acid (H2BDC), N, N-di-methyl formamide (DMF), 3,3′,5,5′-tetramethylbenzidine (TMB), dimethyl sulfoxide (DMSO), hydrogen peroxide (H2O2), Tris-EDTA, HCl (for preparing TE buffer), Sodium Phosphate Dibasic Heptahydrate, Sodium Phosphate Monobasic Monohydrate (for preparing PB buffer), Sodium Acetate, Acetic Acid (for preparing Acetate Buffer) were purchased from Merck Millipore and Sigma-Aldrich (USA). All materials were of analytical reagent grade, and deionized water with 18.2 MΩ resistivity was obtained from a Millipore Milli-Q system. Human serum samples were provided by Milad Hospital, and all synthetic oligonucleotide sequences included in Table S1 were acquired from Metabion International AG (Planegg, Germany).
Dehnoei M., Ahmadi-Sangachin E, & Hosseini M. (2024). Colorimetric and fluorescent dual-biosensor based on zirconium and preasodium metal-organic framework (zr/pr MOF) for miRNA-191 detection. Heliyon, 10(6), e27757.
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5

Synthesis of MIL-101(Cr) Metal-Organic Framework

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The MIL-101(Cr) was synthesized by a following procedure reported previously. Cr(NO3)3·9H2O (99%+, from Aldrich), 1,4-benzene dicarboxylic acid (H2BDC, 99.0%+, from Acros), HF (48%, from Merck) were used as received without further purification.35 (link) A typical synthesis involves a solution containing chromium(iii) nitrate Cr(NO3)3·9H2O (400 mg, 1 × 10−3 mol), 1 × 10−3 mol of fluorhydric acid, 1,4-benzene dicarboxylic acid H2BDC (164 mg, 1 × 10−3 mol) in 4.8 ml H2O (265 × 10−3 mol); the mixture is introduced in a hydrothermal bomb which is put during 8 h in an autoclave held at 220 °C. Then, the solution was filtered and the green colored precipitate was washed with DMF and ethanol (10 mL × 3 times) successively. Finally, the fine green colored crystals were obtained and dried in a vacuum oven at 150 °C overnight.
Jin W.W., Li H.J., Zou J.Z., Zeng S.Z., Li Q.D., Xu G.Z., Sheng H.C., Wang B.B., Si Y.H., Yu L, & Zeng X.R. (2018). Conducting polymer-coated MIL-101/S composite with scale-like shell structure for improving Li–S batteries. RSC Advances, 8(9), 4786-4793.
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6

Synthesis of Metal-Organic Frameworks

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Zirconium (IV) chloride (ZrCl4), 1,4-benzenedicarboxylic acid (H2BDC), 2-aminoterephthalic acid, and hydrochloric acid (37%) were obtained from Merck Company, Germany. Polyvinylidene fluoride (PVDF), sodium fluoride, and N,N′-dimethylformamide (DMF) were supplied by Sigma-Aldrich, Darmstadt, Germany.
Mohamed A., Sanchez E.P., Bogdanova E., Bergfeldt B., Mahmood A., Ostvald R.V, & Hashem T. (2021). Efficient Fluoride Removal from Aqueous Solution Using Zirconium-Based Composite Nanofiber Membranes. Membranes, 11(2), 147.
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