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Copper 2 nitrate trihydrate

Manufactured by Merck Group
Sourced in Germany, United States, India

Copper (II) nitrate trihydrate is a chemical compound with the formula Cu(NO3)2•3H2O. It is a crystalline, blue-green solid that is soluble in water. The compound is commonly used in various laboratory applications, serving as a source of copper ions and as a reagent in analytical chemistry and synthetic processes.

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77 protocols using copper 2 nitrate trihydrate

1

Biosynthesis of Silver and Copper Nanoparticles

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All the chemicals utilized throughout the investigation were of extremely high-purity and analytical grade, and did not undergo any additional purification steps. Silver nitrate (AgNO3) (purity-99.0%), Copper(II) nitrate trihydrate (Cu(NO3)2·3H2O) (purity-99.99%), and ethanol (purity-95.00%) were purchased from Sigma Aldrich. The stock solutions of (AgNO3 = 0.01 mol. dm−3) and (Cu(NO3)2 = 0.01 mol. dm−3) were prepared in double distilled water and then stored in a dark environment for further use. Our investigation utilized plant material from the local market in Jeddah, which is located in the Kingdom of Saudi Arabia.
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2

Polyelectrolyte Multilayer Coatings

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Poly(isobutylene-alt-maleic anhydride) (PIAMA, Mw: 6 kDa), poly(allylamine hydrochloride) (PAH, Mw: 58 kDa), l-histidine methyl ester dihydrochloride, 3-aminopropyltrimethoxysilane (APTMS), N,N-diisopropylethylamine (DIPEA), copper(ii) nitrate trihydrate (Cu(NO3)2 × 3H2O), sodium chloride, sea salt and sodium hydroxide (all from Sigma Aldrich), N,N-dimethylformamide (DMF), dimethylsulfoxide (DMSO), toluene, methanol, acetone and isopropanol (all from Tedia) were used directly as received without further purification. Dialysis membrane tubing (MWCO: 3.5 kD) was received from Fisher Scientific. Silicon wafers (Latech Scientific Supply Pte. Ltd) were 0.6 mm thick, with one side polished and with a natural silicon dioxide layer. QSX 303 Silicon dioxide 50 nm quartz crystal microbalance (QCM) chips were obtained from Analytical Technologies Pte Ltd. Deionized (DI) water with 18 MΩ cm–1 resistivity was obtained from a Millipore Nanopure system.
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3

Synthesis and Characterization of Metal-Organic Frameworks

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Zinc acetate dihydrate (CAS NO: 5970-45-6), Copper (II) nitrate trihydrate (CAS NO: 10031-43-3), 1,3,5-Benzenetricarboxylic acid (CAS NO: 554-95-0), Sodium alginate (CAS NO: 9005-38-3), Potassium Hydroxide (CAS NO: 1310-58-3), Triethylamine (CAS NO: 121-44-8), Ethanol (CAS NO: 64-17-5), MEthanol (CAS NO: 67-56-1), N, N-Dimethylformamide (DMF) (CAS NO: 68-12-2), Hydrochloric acid (CAS NO: 7647-01-0), and Sodium hydroxide (CAS NO: 1310-73-2) with a purity of more than 99% were procured from Sigma Aldrich. Doxycycline and Naproxen were procured from Iran Daru Pharmaceutical Company of Iran with a purity of 98%. Table 1reports the physical and chemical attributes of the drugs studied.

The attributes of Doxycycline and Naproxen (Damiani et al., 2002 ; Papich et al., 2013 (link)).

Table 1
DrugsDoxycyclineNaproxen
Chemical FormulaC22H24N2O8C14H14O3
Molecular weight (g/mol)444.4230.26
Water solubility (μg/L)5000015900
pka3.094.15
λmax (nm)360432
Drug structureImage 1Image 2
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4

Trace Metal Analysis of Food Samples

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All chemicals used in the present study were of the analytical grade. Quinine hemisulfate salt, ethylenediaminetetraAcetic acid, mercury(ii) nitrate, lead(ii) nitrate, cobalt(ii) nitrate hexahydrate, zinc(ii) nitrate hexahydrate, copper(ii) nitrate trihydrate, and cadmium(ii) nitrate tetrahydrate were purchased from Sigma-Aldrich, Germany. Sodium phosphate monobasic, disodium phosphate, sodium acetate, sodium chloride, calcium(ii) nitrate tetrahydrate, iron(iii) chloride hexahydrate, and iron(ii) sulfate were obtained from QReC™, New Zealand. Aluminium(iii) chloride, manganese(ii) sulfate monohydrate, nickel(ii) chloride, silver(i) chloride, and magnesium chloride were procured from Carlo Erba, Italy. Chromium(iii) nitrate and potassium dichromate were purchased from Acros Organics™, USA. Acetic acid was supplied by Merck, Germany. Hydrogen peroxide was purchased from Ajax Finechem, Australia. All food samples and shallot were obtained from the local market of Thailand.
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5

Synthesis and Characterization of Metal Nanoparticles

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Pure ethanol and methanol were purchased from E. Merck Co. (Darmstadt, Germany). Sulfarhodamine, 2, 2 diphenyl-1-picrylhydrazyl (DPPH), were purchased from Sigma-Aldrich (St. Louis, MO, USA). Butylated hydroxyl toluene (BHT), Silver nitrate, zinc nitrate hexahydrate, Copper (II) nitrate trihydrate, Lanthanum Nitrate Hexahydrate, ferric chloride and Sodium hydroxide were purchased from Sigma-Aldrich (St. Louis, MO, USA). The MTT solution was purchased from BIO BASIC CANADA INC.
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6

Synthesis of Metal-Doped Tin Oxide Materials

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The following
chemicals, all purchased from Sigma-Aldrich, were employed as supplied:
copper(II) nitrate trihydrate (99%, Cu(NO3)2·3H2O), ammonium metatungstate hydrate (99%, (NH4)6H2W12O40·xH2O), citric acid (99%), boric acid (99%) and
ethanol (99%). Molybdenum(VI) oxide bis(2,4-pentanedionate) (99%,
C10H14MoO6) was an Alfa Aesar product.
Fluorine-doped 2 mm thick tin oxide (FTO) glass was purchased from
Pilkington Glass (TEC-7).
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7

Catalytic Synthesis of Valuable Chemicals

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Titanium (IV) oxide (P25, TiO2, 99.5%), phosphotungstic acid hydrate (H3O40PW12·xH2O, Mw = 2880.05), zinc nitrate hexahydrate (Zn(NO3)2·6H2O, ≥99.0%), iron(III) nitrate nonahydrate (Fe(NO3)3·9H2O, ≥98%), ammonium metavanadate(V) (NH4VO3, 99%), cobalt(II) nitrate hexahydrate (Co(NO3)2·6H2O, 98%), cerium(III) nitrate hexahydrate (Ce(NO3)3·6H2O, 99%), gallium(III) nitrate hydrate (Ga(NO3)3·xH2O, 99.9%), copper(II) nitrate trihydrate (Cu(NO3)2·3H2O, 99–104%), silver nitrate (AgNO3, ≥99.0%), palladium(II) nitrate hydrate (Pd(NO3)2·xH2O, 99.9%) and dimethyl carbonate (DMC, ≥99.0%) were purchased from Sigma-Aldrich and used without further purification. 13C labeled carbon dioxide (13CO2, 99 atom% 13C - <3 atom% 18O) was purchased from Cortecnet.
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8

Quantitative Analysis of Metal Ions

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Standard solutions of five target metal ions were copper(II) nitrate trihydrate (Sigma-Aldrich), cobalt(II) chloride (Sigma-Aldrich), mercury(II) chloride (Sigma-Aldrich), nickel(II) sulfate hexahydrate (Alfa Aesar), and manganese(II) chloride tetrahydrate (Chem-Impex International Inc). Interfering ions were potassium nitrate (Sigma-Aldrich), sodium nitrate (Aldrich), magnesium chloride hexahydrate (Alfa Aesar), and calcium nitrate tetrahydrate (Alfa Aesar) as common ions found in waters and cadmium(II) nitrate tetrahydrate (Sigma-Aldrich), lead(II) nitrate (Sigma-Aldrich), zinc(II) nitrate hexahydrate (Sigma-Aldrich), potassium dichromate (Alfa Aesar), iron(III) chloride (Sigma-Aldrich), iron(II) sulfate heptahydrate (Sigma-Aldrich), vanadium(III) chloride (Sigma-Aldrich) were also studied.
Metal ion solutions were prepared in acetate buffer (0.1 M, pH 5.0). Acetate buffer was prepared by dissolving sodium acetate (Merck) and acetic acid (Sigma-Aldrich) in Milli-Q water (Millipore Milli-Q purification system, R ≥ 18.2 MΩ cm−1). Complexing agents, masking agents, and all reagents were prepared and used without purification as shown in Table S1 and S2.
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9

Synthesis and Characterization of Gold Nanoparticles

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Gold(III) chloride trihydrate
(≥99.9%), intercalator ligand 1,10-phenanthroline (≥99%), l-cysteine (≥97%), and copper(II) nitrate trihydrate
(98.0–103%) were purchased from Sigma-Aldrich (USA). Tri-sodium
citrate dihydrate (99.95%) was purchased from Fisher Scientific. All
the chemicals obtained were of analytical grade and were used as received.
All the solutions for copper complex synthesis and gold nanoparticle
synthesis were prepared using Milli-Q water.
Fourier transform
infrared (FTIR) spectra were recorded as KBr pellets in the 4000–400
cm–1 range on a PerkinElmer spectrometer. The ultraviolet–visible
(UV–vis) spectra of a sample dissolved in ultrapure water were
recorded on a PerkinElmer Lambda 25 spectrophotometer in the 200–900
nm range. The electrospray ionization mass spectrometry (ESI-MS) spectra
of the sample in water–methanol solutions were recorded from
50–1000 m/z on a PerkinElmer
benchtop quadrupole ion trap mass spectrometer (Flexar SQ300) with
the capillary temperature set to 60 °C.
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10

Copper-Catalyzed Organic Synthesis

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All chemicals and solvents were purchased from commercial vendors and were then used without any further purification. N,N-dimethylformamide, >99.6%; dimedone, >98%; and ethanol, 100% was purchased form Fisher Scientific (Waltham, MA). 1,3,5-benzenetricarboxylic acid, >98%; and copper (II) nitrate trihydrate, >99%; 3,3,6,6-tetramethyl-9-phenyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8 (2H)-dione; and benzaldehyde, >99% were purchased from Sigma-Aldrich (St. Louis, MA). All deionized water used was purified by a Millipore Milli-Q-IQ 7000 water purification system to 18.2 MΩ-cm resistivity prior to use.
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