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1

Synthesis of Carbazole Derivatives

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Reagents and solvents were obtained from commercial sources and used as received. Carbazole (95%), acetic anhydride (99%), copper (II) nitrate trihydrate (98%), and acetic acid (99.8%) were obtained from Sigma-Aldrich. Dimethoxymethane (95%) and palladium on activated carbon, 10% Pd/C, were purchased from Acros. 1-Fluoro-4-nitrobenzene (99%), potassium carbonate (99%), potassium hydroxide (KOH, 90%), trifluoromethanesulfonic acid (F3CSO3H, 98%), and hydrazine hydrate (98%) were ordered from Alfa Aesar. Methanol (99.8%), acetone (99.5%), ethylacetate (EA, 99.8%), petroleum ether (≥90%), tetrahydrofuran (THF, 99.9%), ethanol (99.8%), and dichloromethane (DCM, 99.8%) were obtained from Showa (Tokyo, Japan).
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2

Benzophenone Photocatalytic Reduction

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Benzophenone (99%), potassium carbonate (K2CO3, 99.9%), titanium tetrachloride (TiCl4, 99.9%), zinc (Zn, 98%), and 1,2-dichloroethane (DCE, 99.8%) were ordered from Alfa Aesar. Anhydrous magnesium sulfate (MgSO4, 99.5%), ethylacetate (EA), tetrahydrofuran (THF), acetone, methanol (CH3OH), and dichloromethane (DCM) were purchased from Showa (Tokyo, Japan).
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