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8 protocols using thiourea ch4n2s

1

Synthesis and Characterization of Thiourea Catalysts

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All chemical reagents used in the experiments were obtained from commercial sources as guaranteed grade reagents. Thiourea CH4N2S (molecular weight 76.12 g/mol, purity ≥ 99.0%), ammonium molybdate (NH4)2MoO4 (molecular weight 196.01 g/mol, purity ≥ 99.98%), ammonium perrhenate NH4ReO4 (molecular weight 268.24 g/mol, purity ≥ 99.0%), and Pt/C 10% (molecular weight 195.08, purity 9.8–10.2%) were purchased from Sigma-Aldrich. All chemical reagents were of analytical grade and utilized without any further purification.
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2

MoS2 Nanofiltration Membrane Performance

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42.0 mm-long Al2O3 tubular ceramic substrate with 9.0 mm inner and 13.0 mm outer diameters were supplied by Jiexi Lishun Technology Co. Ltd. (Guangdong, China). The average pore size of the Al2O3 tubular substrate was 50.0 nm ± 10 nm. Ammonium molybdate tetrahydrate ((NH4)6Mo7O24·4H2O) and thiourea (CH4N2S) were purchased from Sigma Aldrich Co. (USA). In order to test the separation performance of MoS2 nanofiltration membrane, five polar solvents (methanol, ethanol, propanol, acetonitrile and acetone) and one non-polar solvent (n-hexane) were selected. Six different solvents were selected, including five polar solvents (methanol, ethanol, propanol, acetonitrile and acetone) and one non-polar solvent (n-hexane). The solute was drug small molecule acetaminophen. All solvents and solutes were purchased from Beijing Chemical Factory (Beijing, China). The purity of all the solvents were analytical pure and all chemicals were used as received without further purification.
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3

SARS-CoV-2 Spike Protein Binding Assay

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All chemicals were of analytical grade and they were used without further purification steps. Strontium titanate (SrTiO3), palladium nanoparticles trapped in aluminum hydroxide matrix (Pd/AlO(OH)), 2-[4-(2-hydroxyethyl) piperazine-1-yl] sulfonic ethane (HEPES), chitosan (1%), glutaraldehyde (5%), bovine albumin (BSA) (1%), and thiourea (CH4N2S) were purchased from Sigma-Aldrich, USA.
Anti-SARS-CoV-2 spike glycoprotein S1 antibody (Ab273074) and SARS-CoV-2 spike glycoprotein S1 (Ab272105) were purchased from abcam, USA. These proteins were denoted as anti-SARS-CoV-2 and SARS-CoV-2, respectively. Monobasic sodium phosphate (NaH2PO4.H2O), acetic acid (CH3COOH), sodium hydroxide (NaOH), ascorbic acid (C6H8O6 or AA), and boric acid (H3BO3) were purchased from Isofar - Indústria e Comércio de Produtos Químicos Ltda, Brazil. Ethanol was purchased from Merck - Brazil. All working solutions were prepared with water purified in an OS100LXE system from GEHAKA Company.
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4

Solvothermal Synthesis of ZnO Nanostructures

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All analytical-grade sodium hydroxide (97%), ethanol (>99%), citric acid (C6H8O7), thiourea (CH4N2S), zinc acetate dihydrate (ZAD), zinc nitrate hexahydrate (ZNH), hexamethylenetetramine (HMTA), polyethylenimine (PEI), sodium sulphate (Na2SO4), and the fluorine-doped tin oxide (FTO) conductive glass substrates having sheet resistance around 10–14 Ω cm−2 were purchased from Sigma-Aldrich, Merck, KGaA, Darmstadt, Germany. All solutions were made with deionized water that had been doubly distilled.
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5

Synthesis and Hydrogen Evolution Catalysts

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All chemicals in the experiments were used without further purification. All catalyst syntheses and hydrogen evolution reactions were performed with deionized (DI) water. Thiourea (CH4N2S, ≥99%), triethanolamine (TEOA, C6H15NO3, 99%), and chloroplatinic acid hexahydrate (H2PtCl6.6H2O) were purchased from Sigma-Aldrich (Gyeonggi, Korea). Ethyl alcohol (C2H5OH, 99.9%) was obtained from Daejung Chemicals and Metals Co., Ltd. (Gyeonggi, Korea).
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6

Synthesis of Dye-Sensitized Solar Cells

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All reagents and materials were analytical grade and used without future purification. Ferric nitrate nonahydrate [Fe(NO3)3⋅9H2O], thiourea [CH4N2S] were supplied from Sigma Aldrich, while titanium chloride (TiCl4), ethylene glycol (EG), potassium iodide (KI), iodine (I2) and ruthenium N719 dye were procured from Merck Co.
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7

Synthesis and photocatalytic activity of ZnS-MnS

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As precursors of Zn, S and Mn zinc nitrate hexahydrate (Zn(NO3)2٠6H2O) (>99%), thiourea (CH4N2S) (99%) and manganese acetate tetrahydrate (Mn(CH3COO)2٠4H2O) (>99%) used were from Sigma-Aldrich (Poznan, Poland). As solvents and, at the same time, stabilizers, we used two commonly applied amines, i.e. ethylenediamine (C2H8N2) (>99%, Sigma-Aldrich) and hydrazine monohydrate (N2H4) (98%, Sigma-Aldrich). For the photocatalytic tests, rhodamine B (RhB) (99%, Sigma-Aldrich, CAS no. 81-88-9) and P25 TiO2 (≥99.5%, Sigma-Aldrich) were utilized. All chemicals were used as received without further purification.
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8

Synthesis of Molybdenum-based Electrodes

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Sodium molybdate (Na2MoO4·2H2O) and thiourea (CH4N2S) were purchased from Sigma-Aldrich. Hydrochloric acid (HCl) was purchased from VWR Chemicals (USA). Sodium sulfite (Na2SO3), polyvinylidene fluoride (PVDF) and acetylene black were bought from Alfa Aesar. The deionized water was supplied by a Water Purifier system. All the chemicals were used as received without further purification.
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