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Iron 3 nitrate nonahydrate

Manufactured by Merck Group
Sourced in United States, Germany, United Kingdom

Iron(III) nitrate nonahydrate is a chemical compound with the formula Fe(NO3)3·9H2O. It is a crystalline solid that is commonly used as a laboratory reagent and in various industrial applications. The compound consists of iron(III) ions and nitrate ions, along with nine water molecules. It is soluble in water and is typically used in chemical synthesis, analysis, and other research applications that require a source of iron(III) ions.

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86 protocols using iron 3 nitrate nonahydrate

1

Analysis of St. John's Wort Extracts

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All reagents were of analytical
reagent grade. Dried St. John’s wort was obtained from a local
market. Sodium fluoride (NaF) was purchased from La Chema, Czech Republic.
Aluminum nitrate nonahydrate (Al(NO3)3·9H2O) and ethylenediaminetetraacetic acid disodium salt dihydrate
(Na2EDTA) were purchased from Sigma-Aldrich. Methyl salicylate
(99.2% pure, 2-(HO)C6H4CO2CH3) was obtained from JQC (Huayin) Pharmaceutical Co., Ltd.,
and sodium acetate (CH3COONa), acetic acid (CH3COOH), ethanol, iron(III) nitrate nonahydrate (Fe(NO3)3·9H2O), iron(II) chloride tetrahydrate (FeCl2·4H2O), manganese(II) nitrate tetrahydrate
(Mn(NO3)2·4H2O), ammonium chloride
(NH4Cl), potassium nitrate (KNO3), calcium nitrate
tetrahydrate (Ca(NO3)2·4H2O),
magnesium nitrate hexahydrate (Mg(NO3)2·6H2O), sodium nitrate (NaNO3), sodium chloride (NaCl),
sodium bromide (NaBr), sodium sulfate (Na2SO4), and boric acid (H3BO3) were purchased from
Merck. Sodium phosphate monobasic (NaH2PO4)
was obtained from Riedel-de Haen.
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2

Synthesis of Magnetite Nanoparticles using Thermal Pyrolysis

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Magnetite nanoparticles were synthesized by a thermal pyrolysis method, using HDA as a stabilizing agent. Analytically pure reagents were used as the starting materials without further purification. In a typical synthesis process, 12.2 g of 1–hexadecylamine (Fisher Scientific International, Inc., Pittsburgh, PA, USA) was melted at 80 °C in a round-bottom flask, and then 2.9 g of iron (III) nitrate nonahydrate (Merck Millipore, Burlington, MA, USA) (Fe(NO3)3·9H2O) was dissolved in it. To remove water from iron nitrate, the mixture was heated to 120 °C for 30 min under magnetic stirring. To obtain nanoparticles with different sizes, the mixture was heated to the final temperature of the reaction (TR), which was varied from 200 to 380 °C and held at appropriate temperatures for 1 h. After completion of the reaction, the resulting black solution was cooled to 70 °C and washed several times with toluene, which ensures complete removal of HDA from the samples.
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3

Analytical Determination of Aldehydes and Ketones

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Propanal, pentanal, hexanal, heptanal, octanal, nonanal, trans-2-butenal, trans-2-pentenal, trans-2-hexenal, trans-2-heptenal, trans-2-octenal, trans-2-nonenal, trans-2-decenal, trans-2-undecenal (≥95%), trans,trans-2,4-heptadienal, trans,trans-2,4-decadienal, 1-penten-3-ol, 2-heptanone, 2-octanone, 2-pentylfuran, 2-ethylfuran, 2-butyl-2-octenal, 2-methyl-2-pentenal, propanoic acid, caproic acid, iron(II) chloride (tetrahydrate), iron(III) nitrate (nonahydrate), and iron(II) sulphate (heptahydrate) were obtained from Merck KGaA, Darmstadt, Germany. Acetic acid, chloroform, potassium iodide and acetonitrile were purchased from Carl Roth GmbH + Co. KG, Karlsruhe, Germany. Sodium thiosulphate (0.1 N) was purchased from Bernd Kraft GmbH, Duisburg, Germany. 1,2-Dipalmitoyl-sn-glycero-3-phosphoethanolamine (PE, >96%), and 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (PC) were obtained from TCI Chemicals Europe N.V., Zwijndrecht, Belgium. Paraffin oil (Pfeiffer® P3) was purchased from MasCom Technologies GmbH, Bremen, Germany. All of the chemicals were of analytical grade, if not mentioned otherwise.
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4

Synthesis of Metal-Organic Composites

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All chemicals were commercially available and used as received unless otherwise stated. Tetrahydrofuran (THF) and dimethylformamide (DMF), both p.a. grade, were purchased from VWR Chemicals (Darmstadt, Germany), sulfur was purchased from Carl Roth GmbH and Co. KG (Karlsruhe, Germany). Diisopropenylbenzene (DIB) was purchased from TCI chemicals (Eschborn, Germany). N-benzylmethylamine, mercury(II) chloride, cadmium nitrate tetrahydrate, cobalt(II) nitrate hexahydrate, zinc nitrate hexahydrate, and lead(II) nitrate were purchased from Sigma Aldrich (Munich, Germany). Nitric acid (65%) was purchased from Th. Geyer GmbH and Co. KG. (Hamburg, Germany). Copper(II) nitrate trihydrate, l-cysteine, and Iron(III) nitrate nonahydrate were purchased from Merck KGaA (Darmstadt, Germany), and Poly(methyl methacrylate) (PMMA) (Mw = 109,000 g/mol, Mw/Mn = 1.86) was gratefully granted by Evonik Industries AG (Essen, Germany).
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5

Synthesis and Antimicrobial Evaluation of Novel Bismuth Nitrate Formulations

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Nitric acid (65%), iron (III) nitrate nonahydrate (Fe(NO3)3, MW = 403.95 g/mol), bismuth (III) nitrate (Bi5O(OH)9(NO3)4, MW = 1.462 g/mol), and dichloromethane (DCM) were acquired from Merck KGaA, Darmstadt, Germany. Ammonia solution (25%, MW = 35.05 g/mol) was purchased from ISOLAB (Wertheim, Germany). PCL (MW = 80,000) was purchased from Sigma Aldrich (Gillingham, UK). Distilled water was supplied by a water distiller (Liston). Q (CAS: 6151-25-3) was obtained from Sigma-Aldrich, Taufkirchen, Germany. Antimicrobial assay: Staphylococcus (S.) aureus ATCC 6538, Escherichia (E.) coli ATCC 8739, Pseudomonas (Ps.) aeruginosa ATCC 9027 and Candida (C.) albicans ATCC 10231 was provided by American Type Culture Collection (ATCC, Manassas, VA, USA).
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6

Synthesis and Characterization of Metal-Organic Frameworks

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Chromium nitrate nonahydrate (Cr(NO3)3·9H2O, 98%), cobalt nitrate hexahydrate (Co(NO3)2·6H2O, 98.5%), terephthalic acid (TPA, 98%), sodium hydroxide (NaOH), iron(iii) nitrate nonahydrate (Fe(NO3)3·9H2O, 98%), dimethyl formamide (DMF, 99%), ethanol (C2H5OH, 96%), disodium ethylenediaminetetraacetate (Na2EDTA, 99%), silver nitrate (AgNO3, 98%), 1,4-benzoquinone (BQ, 98%), t-butyl alcohol (t-BuOH, 99%), Rhodamine B (RhB, C28H31ClN2O3, 98%), methyl orange (MO, C14H14N3NaO3S, 98%) and other chemicals were obtained from Merck Company and used as received.
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7

Synthesis and Characterization of Metal-Curcumin Complexes

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Curcumin, copper(II) sulfate pentahydrate (CuSO4·5H2O), zinc(II) chloride (ZnCl2) and iron(III) nitrate nonahydrate (Fe(NO3)3·9H2O) were purchased from Merck (Germany). Solvents with highest purity were bought from Merck (Germany) and used without further purifications. The elemental analyses (carbon, hydrogen and nitrogen) of complexes were obtained from a Carlo ERBA Model EA 1108 analyzer. The metal content of the complexes was determined by atomic absorption analysis on a Varian Spectra AA-220 equipment. Fourier transform infrared (FT-IR) spectroscopy was performed using a FT-IR Spectrometer Bruker Tensor 27 as KBr disks. Fresh stock solution of metal-CUR complexes (Cu-CUR, Zn-CUR, Fe-CUR) and free-CUR were prepared in dimethyl sulfoxide (DMSO) at the concentration of 1 mg/ml. N-Acyl-homoserine lactone (C6-HSL) (Sigma-Aldrich) was used at 20 µM in C. violaceum CV026 biosensor bioassay.
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8

Synthesis of Metal-Substituted Aluminophosphates

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Aluminum isopropoxide (Merck), orthophosphoric acid (85% in H2O, Sigma Aldrich), and triethylamine (TEA, Merck) were used as precursors for AlPO4-5 growth. Tetraethyl orthosilicate (Merck), magnesium chloride (Merck), cobalt (II) acetate tetrahydrate (98%, Sigma-Aldrich), and iron (III) nitrate non-ahydrate (Merck) were used as metal precursors for the synthesis of the metal-substituted AlPOs (MeAPO-5).
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9

Synthesis of Metal-Organic Nanocomposites

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Nb foil (99%) was obtained from Alfa Aesar, ammonium fluoride [NH4F, 99.9%], ammonium persulphate [(NH4)2S2O8, 98.5%], ammonium sulfate [(NH4)2SO4, 99.0%], nickel(ii) nitrate hexahydrate [Ni(NO3)2·6H2O, 97%], iron(iii) nitrate nonahydrate [Fe(NO3)3·9H2O, 98%], and urea [CO(NH2)2] were purchased from Merck, ethanol (C2H5OH, 99.9%), acetonitrile (CH3CN, 99.9%), and benzylamine (C7H9N, 99%) were purchased from Energy Chemical. All chemical reagents were all used as received.
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10

Electrochemical Synthesis of Transition Metal Catalysts

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An EG&G
Model 273 Potentiostat/Galvanostat was used for the electrochemical
measurements. The electrochemical system used consisted of three electrodes:
nickel foam, rectified with the catalyst, as the working electrode;
Ag/AgCl as the reference electrode; and stainless steel sheet as the
counter electrode (all electrodes were purchased from Azar Electrode
Company, Urmia, Iran). Iron(III) nitrate nonahydrate (Fe(NO3)3·9H2O), cobalt(II) nitrate hexahydrate
(Co(NO3)2·6H2O), manganese(II)
sulfate monohydrate (MnSO4·H2O), potassium
permanganate (KMnO4), potassium hydroxide (KOH, ≥97.0%),
2-propanol (CH3CHOHCH3), and ethylene glycol
((CH2OH)2) were purchased from Merck and used
for the experiments. Distilled water was used to prepare the chemical
solutions. All these materials were purchased from Merck (Germany).
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