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2 protocols using manganese sulphate monohydrate

1

Adsorption Study of Heavy Metals

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Dodecyl amine (98%), tetraethyl orthosilane (TEOS, 98%) and 3-aminopropyl triethoxysilane (APTES, 99%) were purchased from Sigma Aldrich. AR grade 1,5- Diphenylcarbazide (DPC 98%) was obtained from Loba Chemie. Sulphuric acid (98%) and ethanol (99%) were obtained from Rankem. Potassium dichromate (99%), 0.1 N Hydrochloric acid, 0.1 N sodium hydroxide were purchased from Merck. Silica, Mesoporous SBA-15 (< 150 µm particle size and 450–550 m2 g−1 surface area, Catalogue number: 806854) was obtained from Sigma Aldrich. Lead nitrate, Copper sulphate pentahydrate, Ammonium ferrous sulphate hexahydrate, Nickel sulphate pentahydrate, Manganese sulphate monohydrate, Chromium(III) nitrate nonahydrate, Magnesium sulphate heptahydrate, Cadmium nitrate heptahydrate, Zinc nitrate hexahydrate, Barium chloride dihydrate were purchased from Merck. All experiments were conducted using ultrapure water obtained from a MilliQ system.
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2

Synthesis and Characterization of Ciprofloxacin Compounds

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Analytical grade chemicals were used throughout the research work and no further purification was carried out. Required chemicals were zinc sulphate heptahydrate (Scharlau, Spain, EU), Manganese sulphate monohydrate, sodium sulphide monohydrate, thioglycolic acid, (TGA), and ethanol from Merck (Darmstadt Germany), phosphoric acid, acetic acid, boric acid, hydrochloric acid and sodium hydroxide (Sigma-Aldrich, St. Louis, USA). Standard reference of ciprofloxacin was thankfully received from Shaheen pharmaceutical Industry in Swat. Commercial formulations of ciprofloxacin such as ciproquine and ciprol were brought from local market.
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